139391-16-5

Basic information

• Product Name: O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-6)-2-pyridyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranoside
• CAS NO: 139391-16-5
• Molecular Weight: 1354.58
• Mol File: 139391-16-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-6)-2-pyridyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-6)-2-pyridyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranoside(139391-16-5)
• EPA Substance Registry System: O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-6)-2-pyridyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranoside(139391-16-5)

Safety Data

• Hazardous Substances Data: 139391-16-5(Hazardous Substances Data)

Upstream product

• 139391-15-4 2-pyridyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-1-thio-β-D-glucopyranoside 
• 139391-11-0 2-pyridyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranoside 
• 2297-41-8 pyridin-2-yl 1-thio-β-D-glucopyranoside 
• 74352-37-7 (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(pyridin-2-ylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 139391-12-1 Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-(pyridin-2-ylsulfanyl)-tetrahydro-pyran-4-yl ester 

Relevant articles and documents

Directed, Iterative, Stereoselective Synthesis of Oligosaccharides by Use of Suitably 2-O-Substituted 2-Pyridyl 1-Thioglycopyranosides on Activation by Methyl Iodide

The title synthesis is described by the proven methyl iodide activation procedure to obtain the α-linked oligosaccharides.Key words: Reiterative α-glycosidation; 2-pyridyl-1-thioglycopyranosides; armed-disarmed phenomena