139884-19-8

Basic information

• Product Name: Benzoic acid, 4-(methoxymethoxy)-, methyl ester
• CAS NO: 139884-19-8
• Molecular Formula: C10H12O4
• Molecular Weight: 196.203
• Mol File: 139884-19-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(methoxymethoxy)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(methoxymethoxy)-, methyl ester(139884-19-8)
• EPA Substance Registry System: Benzoic acid, 4-(methoxymethoxy)-, methyl ester(139884-19-8)

Safety Data

• Hazardous Substances Data: 139884-19-8(Hazardous Substances Data)

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 13057-17-5 bromethyl methyl ether 
• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 98491-29-3 1-iodo-4-(methoxymethoxy)benzene 
• 4382-76-7 methoxymethyl acetate 
• 109-87-5 Dimethoxymethane 

Downstream Products

• 99-76-3 methyl 4-hydroxylbenzoate 
• 936250-15-6 1-(methoxymethoxy)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene 
• 761001-59-6 (2-fluoro-4-methylphenyl)(4-(methoxymethoxy)phenyl)methanone 
• 761001-61-0 1-(2-(benzyloxy)-5-(2-fluoro-4-methylbenzoyl)phenyl)ethanone 
• 761001-60-9 4-(2-fluoro-4-methylbenzoyl)phenyl acetate 
• 761001-58-5 N-methoxy-4-(methoxymethoxy)-N-methylbenzamide 
• 1345681-72-2 (S)-N-(2-(1-(chloromethyl)-5-hydroxy-9-methyl-2,3-dihydro-1H-benzo[e]indole-3-carbonyl)-imidazo[1,2-a]pyridin-6-yl)-4-(methoxymethoxy)benzamide 
• 25458-44-0 4-(methoxymethoxy)benzoic acid 
• 74754-58-8 Cholest-5-en-3β-yl 4-hydroxybenzoate 
• 156539-49-0 Cholest-5-en-3β-yl 4-methoxymethoxybenzoate 

Relevant articles and documents

First total synthesis of quiquesetinerviusin A

The first total synthesis of the dihydrobenzofuran neolignan quiquesetinerviusin A and its related structure have been described. Phenolic coupling is the key step to constructing the dihydrobenzofuran skeleton with vanillin as the raw material. The hydroxyl group was protected with dihydropyran (DHP) and the ester group was reduced with diisobutylaluminium hydride (DIBAL-H) in order to obtain the crucial intermediate diol, which was then condensed with an acid ligand to give the desired compounds following removal of the protecting groups.

COMPOSITIONS AND METHODS OF MODULATING SHORT-CHAIN DEHYDROGENASE ACTIVITY

Compounds and methods of modulating 15-PGDH activity, modulating tissue prostaglandin levels, treating disease, diseases disorders, or conditions in which it is desired to modulate 15-PGDH activity and/or prostaglandin levels include 15-PGDH inhibitors described herein.

Thieme Chemistry Journals Awardees - Where Are They Now? Bis(2-pyridyl)amides as Readily Cleavable Amides under Catalytic, Neutral, and Room-Temperature Conditions

Mild solvolytic cleavage of bis(2-pyridyl)amide under neutral and room-temperature conditions is described. The inherently stable amide was readily activated by catalytic amounts of metal cations to react with alcohols. Based on X-ray crystallographic analysis, the primary driving force was considered to be amide distortion induced by the metal coordination of two pyridyl groups in a bidentate fashion without affecting the amide functionality. The compatibility of the acid/base-sensitive functionalities and the absence of racemization during solvolysis highlight the mildness of the present protocol.