140136-60-3Relevant articles and documents
Synthesis of a (N,C,C) Au(iii) pincer complex: Via Csp3-H bond activation: Increasing catalyst robustness by rational catalyst design
Holmsen, Marte Sofie Martinsen,Nova, Ainara,Hylland, Knut,Wragg, David S.,?ien-?Degaard, Sigurd,Heyn, Richard H.,Tilset, Mats
, p. 11104 - 11107 (2018)
A (N,CAr,CAlk) Au(iii) pincer complex has been synthesized from Au(OAc)3 (OAc = OCOCH3) and 2-(3,5-di-tert-butylphenyl)pyridine (L1) involving a Csp3-H bond activation by electrophilic substitution. In agreement with DFT calculations, the resulting complex significantly improves the performance of Au(tpy)(OAcF)2 (tpy = 2-(p-tolyl)pyridine, OAcF = OCOCF3) in the catalytic trifluoroacetylation of acetylene.