140140-15-4Relevant articles and documents
Die Hydrolyse Schiffscher Basen - Substituenten- und Loesungsmitteleinfluss. I. Die basische Hydrolyse von 4'-Carboxy-N-(X-benzyliden)anilinen als Zweistufenreaktion in methanolisch-waessriger Loesung - Kinetik und Aktivierungsparameter
Mitzner, R.,Seidel, S.
, p. 1179 - 1185 (2007/10/02)
It is shown that the hydrolysis of some Schiff bases which were resolved in methanol previously give a two step reaction in basic medium. 35 rate constants are correlated with the Hammett's ? constants of the substituent groups, showing that linear relationship exist with ρ= -1,54 and ρ= -0,63, respectively.Activation parameters are given of both first and second step of reaction.