140173-03-1Relevant articles and documents
SYNTHESIS OF OXYGEN-CONTAINING ORGANOFLUORINE COMPOUNDS AND THEIR REACTIONS XI. LIQUID-PHASE OXIDATION OF PERFLUORO-1,5-HEXADIENE BY ATMOSPHERIC OXYGEN
Filyakova, T. I.,Ilatovskii, R. E.,Zapevalov, A. Ya.
, p. 1818 - 1822 (2007/10/02)
The oxidation of perfluoro-1,5-hexadiene by atmospheric oxygen under UV irradiation gave perfluoro-1,5-hexadiene dioxide, 4,5-epoxyperfluorovaleryl fluoride, and perfluorosuccinyl fluoride.The intermediate oxidation product was 1,2-epoxyperfluoro-5-hexene.The obtained α-oxides undergo both nucleophilic and electrophilic opening of the epoxide ring, giving mono- and bifunctional derivatives.