1402063-41-5

Basic information

• Product Name: (R,R)-N-propargyl-N-methyl-N’-4-toluenesulphonyl-1,2-diphenylethylenediamine
• Synonyms: (R,R)-N-propargyl-N-methyl-N’-4-toluenesulphonyl-1,2-diphenylethylenediamine
• CAS NO: 1402063-41-5
• Molecular Weight: 418.56
• Mol File: 1402063-41-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R,R)-N-propargyl-N-methyl-N’-4-toluenesulphonyl-1,2-diphenylethylenediamine(CAS DataBase Reference)
• NIST Chemistry Reference: (R,R)-N-propargyl-N-methyl-N’-4-toluenesulphonyl-1,2-diphenylethylenediamine(1402063-41-5)
• EPA Substance Registry System: (R,R)-N-propargyl-N-methyl-N’-4-toluenesulphonyl-1,2-diphenylethylenediamine(1402063-41-5)

Safety Data

• Hazardous Substances Data: 1402063-41-5(Hazardous Substances Data)

Upstream product

• 144222-34-4 (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine 
• 50-00-0 formaldehyd 
• 1402063-39-1 (R,R)-N-propargyl-N’-4-toluensulphonyl-1,2-diphenylethylenediamine 

Downstream Products

• 1402063-43-7 (R,R)-N-(1-benzyl-1,2,3-triazole-4-ylmethyl)-N-methyl-N’-4-toluenesulphonyl-1,2-diphenylethylenediamine 

Relevant articles and documents

Application of ruthenium complexes of triazole-containing tridentate ligands to asymmetric transfer hydrogenation of ketones

The synthesis of a series of tridentate ligands based on a homochiral 1,2-diamine structure attached to a triazole group and their subsequent applications to the asymmetric transfer hydrogenation of ketones are described. In the best cases, alcohols of up to 93% ee were obtained. Although base is not required, the use of Ru3(CO)12 as metal source is essential, indicating a unique mechanism for the formation of the active catalyst.