14024-61-4

Basic information

• Product Name: Bis(2,4-pentanedionato-O,O')palladium(II)
• Synonyms: bis(2,4-pentanedionato-o,o')palladium(ii);BIS(2,4-PENTANEDIONATO)PALLADIUM(II);BIS(ACETYLACETONATO)PALLADIUM(II);ACETYLACETONE, PALLADIUM(II) DERIVATIVE;ACETYLACETONE PALLADIUM(II) SALT;Palladium acetylacetonate or Palladium(II)2,4-pentanedionate;Bis(acetylacetonato)palladium(II) dec. 205 halide free source of Pd;Bis(acetylacetonato)palladium(Ⅱ)
• CAS NO: 14024-61-4
• Molecular Formula: C10H14O4Pd
• Molecular Weight: 304.64
• EINECS: 237-859-8
• Product Categories: Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal beta-diketonate complexes;chemical reaction,pharm,electronic,materials;Pd
• Mol File: 14024-61-4.mol
• Article Data: 0

Chemical Properties

• Melting Point: 190 °C
• Boiling Point: 138.4 °C at 760 mmHg
• Flash Point: 43.1 °C
• Appearance: Yellow to orange/Solution
• Vapor Pressure: 0.174mmHg at 25°C
• Storage Temp.: Store below +30°C.
• Solubility: Soluble in benzene and chloroform.
• Water Solubility: INSOLUBLE
• BRN: 4136188
• CAS DataBase Reference: Bis(2,4-pentanedionato-O,O')palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(2,4-pentanedionato-O,O')palladium(II)(14024-61-4)
• EPA Substance Registry System: Bis(2,4-pentanedionato-O,O')palladium(II)(14024-61-4)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 36-36/37/38-22
• Safety Statements: 26-37/39
• RIDADR: 3181
• WGK Germany: 2
• TSCA: Yes
• Hazardous Substances Data: 14024-61-4(Hazardous Substances Data)

Usage

Chemical Properties

yellow orange needles

Uses

Different sources of media describe the Uses of 14024-61-4 differently. You can refer to the following data:
1. Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.
2. Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.

General Description

Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.

Flammability and Explosibility

Highlyflammable

Purification Methods

It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]

InChI:InChI=1/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;