1402975-27-2

Basic information

• Product Name: (E)-butyl 3-(3,4-dimethylphenyl)-2-methylacrylate
• CAS NO: 1402975-27-2
• Molecular Weight: 246.349
• Mol File: 1402975-27-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-butyl 3-(3,4-dimethylphenyl)-2-methylacrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-butyl 3-(3,4-dimethylphenyl)-2-methylacrylate(1402975-27-2)
• EPA Substance Registry System: (E)-butyl 3-(3,4-dimethylphenyl)-2-methylacrylate(1402975-27-2)

Safety Data

• Hazardous Substances Data: 1402975-27-2(Hazardous Substances Data)

Upstream product

• 95-47-6 o-xylene 
• 97-88-1 2-methyl-butyl acrylate 

Relevant articles and documents

Direct oxidative coupling of arenes with olefins by Rh-catalyzed C-H activation in air: Observation of a strong cooperation of the acid

A [{RhCl(cod)}2]/CCl3COOH system was developed for the oxidative coupling of non-chelate-assisted arenes with olefins in the presence of catalytic amounts of Cu(OAc)2·H2O as a co-oxidant and oxygen as the terminal oxidant. The acid was an indispensable component in this system and played a very important role in the coupling reaction. This catalytic system was applied to the direct oxidative coupling of a series of arenes and olefins and the corresponding products were afforded in high yields with special chemo- and regioselectivity. This reaction provides an atom-efficient route to vinylarenes, which are widely used in various fine chemicals. Give it some air: A [{RhCl(cod)}2]/CCl3COOH system for the oxidative coupling of arenes and olefins afforded their corresponding products with special chemo- and regioselectivity in high yields. This reaction provides an atom-efficient route to vinylarenes. Copyright