14035-05-3

Basic information

• Product Name: 2,5-ditert-butyl-4-nitroaniline
• Synonyms: 2,5-ditert-butyl-4-nitroaniline
• CAS NO: 14035-05-3
• Molecular Formula: C₁₄H₂₂N₂O₂
• Molecular Weight: 250.33668
• Mol File: 14035-05-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,5-ditert-butyl-4-nitroaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-ditert-butyl-4-nitroaniline(14035-05-3)
• EPA Substance Registry System: 2,5-ditert-butyl-4-nitroaniline(14035-05-3)

Safety Data

• Hazardous Substances Data: 14035-05-3(Hazardous Substances Data)

Upstream product

• 21860-03-7 2,5-di-tert-butylaniline 
• 10472-70-5 2,5-di-tert-butyl-p-dinitrobenzene 

Downstream Products

• 22385-85-9 2-Nitro-4-amino-5-tert.-butyl-phenol 
• 22385-90-6 2-Amino-5-hydroxy-1,4-di-tert-butyl-benzol 
• 14035-07-5 2,5-Di-tert.-butyl-4-nitro-benzoesaeure 
• 22503-23-7 4-bromo-2,5-di-tert-butyl-aniline 
• 22503-24-8 2,5-di-tert-butyl-N,N-dimethyl-4-nitro-aniline 
• 22503-22-6 5-Brom-2-nitro-1,4-di-tert-butyl-benzol 
• 22385-84-8 3,5-Di-tert-butyl-4-nitro-phenol 
• 14035-06-4 2,5-Di-tert.-butyl-4-nitro-benzonitril 

Relevant articles and documents

Synthesis of ortho-phenylenebis(guanidine) derivatives with potential chirality

We report the synthesis and potential chirality of ortho-phenylenebisguanidines (BGs) with substituents at C(3) and C(6). Guanidinylation of 3,6-disubstituted benzene-1,2-diamines with 2-chloro-4,5-dihydro-1,3-dimethyl-1H-imidazolium chloride gave the corresponding BGs. X-Ray crystallography showed that the two guanidine moieties occupy different faces of the benzene ring, creating potential chirality, although optical resolution of tBu-substituted BG by chiral HPLC failed. However, a methylated acyclic bisguanidinium salt (BGms) was obtained as a chiral crystal with a space group of P212121.