1414854-49-1Relevant articles and documents
Microphase Behavior and Enhanced Wet-Cohesion of Synthetic Copolyampholytes Inspired by a Mussel Foot Protein
Seo, Sungbaek,Das, Saurabh,Zalicki, Piotr J.,Mirshafian, Razieh,Eisenbach, Claus D.,Israelachvili, Jacob N.,Waite, J. Herbert,Ahn, B. Kollbe
, p. 9214 - 9217 (2015)
Numerous attempts have been made to translate mussel adhesion to diverse synthetic platforms. However, the translation remains largely limited to the Dopa (3,4-dihydroxyphenylalanine) or catechol functionality, which continues to raise concerns about Dopa
Synthesis of 3,4-dihydroxyphenyl-containing polymeric materials from 1,2-polybutadiene and eugenol via thiol—ene addition
Chapala,Bermeshev,Korchagina,Ashirov,Bermesheva
, p. 1061 - 1066 (2016)
In a search for routes to new promising adhesive materials, 3,4-dihydroxyphenyl groups were introduced for the first time into syndiotactic polybutadiene (1,2-unit content >90%). Two ways of introduction were studied: cross metathesis and thiol—ene addition. Eugenol, an available product of plant origin, was used as a source of 3,4-dihydroxyphenyl groups following the protection of its oxygen-containing groups with Et3SiH in the presence of B(C6F5)3) as a catalyst. A cross metathesis reaction of polybutadiene with modified eugenol in the presence of the Grubbs catalysts of different generations resulted in considerable degradation of the polymer into the corresponding low-molecular-weight products. A new approach involving thiol—ene addition afforded 3,4-dihydroxyphenyl-containing polybutadienes with desired catechol contents and desired molecular weights.
Compound containing catechol and thiol group, and preparation method and use thereof
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Paragraph 0028; 0074; 0075; 0076, (2017/01/26)
The present invention relates to a compound which contains both a catechol group and a thiol group and is represented by chemical formula 1. The present invention further relates to a production method thereof, and a use of the same as a bioadhesive and an antifoulant. In the chemical formula 1, R^1 is either hydrogen or a substituted group represented by chemical formula 2 respectively, and at least one among R^1 has the substituted group represented by chemical formula 2.