1423047-61-3

Basic information

• Product Name: VCl₂[2-(2,6-Me₂C₆H₃)NCH₂(C₅H₄N)](N-2-MeC₆H₄)
• Synonyms: VCl₂[2-(2,6-Me₂C₆H₃)NCH₂(C₅H₄N)](N-2-MeC₆H₄)
• CAS NO: 1423047-61-3
• Molecular Weight: 438.273
• Mol File: 1423047-61-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: VCl₂[2-(2,6-Me₂C₆H₃)NCH₂(C₅H₄N)](N-2-MeC₆H₄)(CAS DataBase Reference)
• NIST Chemistry Reference: VCl₂[2-(2,6-Me₂C₆H₃)NCH₂(C₅H₄N)](N-2-MeC₆H₄)(1423047-61-3)
• EPA Substance Registry System: VCl₂[2-(2,6-Me₂C₆H₃)NCH₂(C₅H₄N)](N-2-MeC₆H₄)(1423047-61-3)

Safety Data

• Hazardous Substances Data: 1423047-61-3(Hazardous Substances Data)

Upstream product

• 882994-68-5 2,6-dimethyl-N-((pyridin-2-yl)methyl)benzenamine 

Relevant articles and documents

Synthesis and structural analysis of (imido)vanadium(V) complexes containing chelate (anilido)methyl-imine ligands: Ligand effect in ethylene dimerization

A series of (imido)vanadium dichlorido complexes containing chelate anionic donor ligands of the type, VCl2(L)(NR) [R = 1-adamantyl (Ad), L = 2-(2,6-Me2C6H3)NCH2(C 9H6N) (2), 8-(2,6-Me2C6H 3)NCH2(C9H6N) (3); L = 2-(2,6-R′2C6H3)NCH2(C 5H4N), R = 2-MeC6H4, R′ = Me (4a), iPr (4b); L = 2-(2,6-Me2C6H 3)NCH2(C5H4N), R = 4-MeC 6H4 (5), 3,5-Me2C6H3 (6)], have been prepared and identified. The reactions with ethylene by 2,3 in the presence of methylaluminoxane (MAO) afforded a mixture of high molecular weight polyethylene and oligomers. Reactions with ethylene by VCl 2[2-(2,6-R′2C6H3)NCH 2(C5H4N)](NAd) (1a,b), 4-6 afforded 1-butene with high selectivities (>92%), and the activities by 4a,b are at the same level as those in 1a,b. The activities by 5,6 were lower than 4a,b and were at the same level of that by VCl2[2-(2,6-Me2C 6H3)NCH2(C5H4N)](NPh). These results thus suggest that both the chelate anionic donor and the imido ligands play a role for both the activity and the selectivity.