1426021-96-6

Basic information

• Product Name: (E)-1-phenylpropan-1-one O-acetyl oxime
• Synonyms: (E)-1-phenylpropan-1-one O-acetyl oxime
• CAS NO: 1426021-96-6
• Molecular Weight: 191.23
• Mol File: 1426021-96-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-phenylpropan-1-one O-acetyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenylpropan-1-one O-acetyl oxime(1426021-96-6)
• EPA Substance Registry System: (E)-1-phenylpropan-1-one O-acetyl oxime(1426021-96-6)

Safety Data

• Hazardous Substances Data: 1426021-96-6(Hazardous Substances Data)

Upstream product

• 127-09-3 sodium acetate 
• 93-55-0 1-phenyl-propan-1-one 
• 23517-42-2 propiophenone oxime 
• 75-36-5 acetyl chloride 

Downstream Products

• 875228-76-5 3-methyl-2,4-diphenylpyridine 
• 16206-34-1 3‐methyl‐2,5‐diphenyl‐1H‐pyrrole 
• 17799-61-0 3,4-dimethyl-2,5-diphenyl-1H-pyrrole 
• 65117-72-8 ethyl 4-methyl-5-phenyl-1H-pyrrole-2-carboxylate 
• 93472-51-6 1-ethyl-3,4-diphenyl-isoquinoline 

Relevant articles and documents

Divergent Iron-Catalyzed Coupling of O-Acyloximes with Silyl Enol Ethers

An iron-catalyzed coupling reaction of O-acyloximes and O-benzoyl amidoximes with silyl enol ethers is reported. The protocol provides access to functionalized pyrroles, 1,6-ketonitriles, pyrrolines and imidazolines via carbon-centered radicals generated from an initially formed iminyl radical. The intramolecular cyclization and ring-opening processes of the iminyl radical take place preferentially over reactions that proceed through a 1,3-hydrogen transfer, providing insights into iron-catalyzed reactions with oxime derivatives. The cheap and environmentally friendly iron catalyst, the broad substrate scope and the functional group compatibility make this protocol useful for synthesis of valuable nitrogen-containing products.