1428551-28-3Relevant articles and documents
Organic electroluminescent host material and application thereof in organic electroluminescent device
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, (2021/07/17)
The invention relates to an organic electroluminescent host material. In an organic light-emitting device, in order to reduce the problems of exciton quenching, efficiency roll-off, device service life shortening and the like caused by too high exciton concentration in a light-emitting layer, a light-emitting layer structure generally adopts a host-guest doping mode. Aiming at different luminescent material systems/luminescent mechanisms, the requirements on the basic performance of the host material are different. The invention designs an organic electroluminescent host material based on a 3,3'-dicarbazole unit and a 9,9'-diphenyl fluorene steric hindrance group end capping. The dicarbazole unit endows the material with good carrier transport performance, and end group steric hindrance can effectively inhibit local aggregation of a light-emitting guest. According to different luminescent material systems, the polarity and size of molecules are adjusted by changing the difference of carbazole N-substituent (R), so that the comprehensive optimization of the device performance is realized.
Method for synthesizing N-aryl carbazole compound by catalyzing reaction of carbazole with aryl hydrazine by using transition metal
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Paragraph 0065-0068; 0100, (2020/12/14)
The invention relates to a method for synthesizing an N-aryl carbazole compound by catalyzing reaction of carbazole with aryl hydrazine through transition metal. According to the method, a transitionmetal salt is used as a catalyst, a carbazole compound and an aryl hydrazine compound are used as reaction substrates, the reaction substrates and an alkali compound are added into a solvent for a reaction for a certain period of time to obtain a reaction solution, and the reaction solution is separated and purified to obtain the N-aryl carbazole compound. According to the method, low-boiling-point acetonitrile is used as a reaction solvent, so post-reaction treatment is easy to carry out; oxygen in the air serves as an oxidizing agent, so reaction conditions are environmentally friendly and safe, cost is low, and excessive oxidation is avoided; an aryl hydrazine compound is used as an arylation reagent, and reaction byproducts only comprise water and nitrogen, so the method is environment-friendly and pollution-free; the transition metal salt is used as the catalyst, the activity of the transition metal salt is high, the use of equivalent noble metals is avoided, and synthesis cost isreduced; and generally speaking, the synthesis method is friendly to environment, simple in process, good in reaction selectivity and high in yield, and has a relatively strong industrial applicationprospect.
ORGANIC MIXTURE, COMPOSITION, AND ORGANIC ELECTRONIC COMPONENT
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, (2020/01/03)
Disclosed in the present application is an organic mixture. The organic mixture comprises two organic compounds H1 and H2. The organic compound H1 has electron transmission performance, and the organic compound H1 satisfies: Δ((LUMO+1)?LUMO)≥0.1 eV, and min((LUMO(H1)?HOMO(H2), LUMO(H2)?HOMO(H1))≤min(ET(H1), ET(H2)). The organic compound H1 and the organic compound H2 are easy to form exciplexes and have balanced electron transmission properties, the organic compound Hi has high stability of electron transmission, and accordingly the efficiency and the service life of related electronic components can be effectively improved, and a feasible solution for improving overall performance of the electronic components is provided.