1431294-81-3Relevant articles and documents
Palladium-catalyzed formal hydroacylation of allenes employing carboxylic anhydrides and hydrosilanes
Fujihara, Tetsuaki,Hosomi, Takuro,Cong, Cong,Hosoki, Tomoya,Terao, Jun,Tsuji, Yasushi
supporting information, p. 4570 - 4574 (2015/03/30)
The formal hydroacylation reaction of allenes has been developed employing carboxylic anhydrides as acyl sources and hydrosilanes as reducing reagents in the presence of a commercially available palladium complex as a catalyst. The reaction affords α,β-unsaturated ketones regio- and stereoselectively. The similar catalyst system is also effective for the reduction of carboxylic anhydrides to the corresponding aldehydes employing hydrosilanes.