143959-23-3

Basic information

• Product Name: Benzene, 1,1'-[(4-nitrophenyl)methylene]bis[2,4-dimethoxy-
• CAS NO: 143959-23-3
• Molecular Formula: C23H23NO6
• Molecular Weight: 409.439
• Mol File: 143959-23-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[(4-nitrophenyl)methylene]bis[2,4-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[(4-nitrophenyl)methylene]bis[2,4-dimethoxy-(143959-23-3)
• EPA Substance Registry System: Benzene, 1,1'-[(4-nitrophenyl)methylene]bis[2,4-dimethoxy-(143959-23-3)

Safety Data

• Hazardous Substances Data: 143959-23-3(Hazardous Substances Data)

Upstream product

• 13707-46-5 N-tosyl-4-nitrobenzaldimine 
• 151-10-0 1,3-Dimethoxybenzene 
• 555-16-8 4-nitrobenzaldehdye 

Relevant articles and documents

Metal- And solvent-free synthesis of aniline- And phenol-based triarylmethanes: Via Br?nsted acidic ionic liquid catalyzed Friedel-Crafts reaction

A beneficial, scalable and efficient methodology for the synthesis of aniline-based triarylmethanes has been established through the double Friedel-Crafts reaction of commercial aldehydes and primary, secondary or tertiary anilines using Br?nsted acidic ionic liquid as a powerful catalyst, namely [bsmim][NTf2]. This protocol was successfully performed under metal- and solvent-free conditions with a broad range of substrates, giving the corresponding aniline-based triarylmethane products in good to excellent yields (up to 99%). In addition, alternative aromatic nucleophiles such as phenols and electron-rich arenes were also studied using this useful approach to achieve a diversity of triarylmethane derivatives in high to excellent yields. This journal is

Ruthenium porphyrin catalyzed friedel-crafts type reaction of arenes with imines

Cationic ruthenium porphyrin complex was found to be an efficient catalyst for the Friedel-Crafts type reaction of arenes with imines. The use of a structurally rigid tetradentate porphyrin as the equatorial ligand and weakly coordinating axial ligand is the key to bring out the catalytic reactivity of ruthenium for the reaction.

Friedel-crafts arylation reactions of N -sulfonyl aldimines or sulfonamidesulfones with electron-rich arenes catalyzed by FeCl 3·6H2O: Synthesis of triarylmethanes and bis-heteroarylarylmethanes

(Figure presented) The FeCl3·6H2O-catalyzed Friedel-Crafts arylation reactions of N-sulfonyl aldimines or sulfonamidesulfones with electron-rich arenes and heteroarenes, which lead to the formation of triarylmethanes and bis-heteroar