1444122-30-8Relevant articles and documents
Programmed selective sp2 C-O bond activation toward multiarylated benzenes
Zhao, Fei,Zhang, Yun-Fei,Wen, Jing,Yu, Da-Gang,Wei, Jiang-Bo,Xi, Zhenfeng,Shi, Zhang-Jie
, p. 3230 - 3233 (2013/07/26)
A variety of important multiarylated benzenes were efficiently synthesized from phloroglucinol derivatives 1 through sequential cross-couplings via Pd-catalyzed C-OTs, Ni-catalyzed C-OC(O)NEt2, and C-OMe bond activation. High selectivity was achieved based on the rational design and inherent diversity in the reactivity of different C-O bonds.