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1446696-31-6

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1446696-31-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1446696-31-6 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,4,6,6,9 and 6 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1446696-31:
(9*1)+(8*4)+(7*4)+(6*6)+(5*6)+(4*9)+(3*6)+(2*3)+(1*1)=196
196 % 10 = 6
So 1446696-31-6 is a valid CAS Registry Number.

1446696-31-6Downstream Products

1446696-31-6Relevant articles and documents

Highly selective copper-catalyzed hydroboration of allenes and 1,3-dienes

Semba, Kazuhiko,Shinomiya, Masataka,Fujihara, Tetsuaki,Terao, Jun,Tsuji, Yasushi

, p. 7125 - 7132 (2013/07/04)

The highly selective copper-catalyzed hydroboration of allenes has been developed. Allylboranes and alkenylboranes were selectively prepared by the judicious choice of catalytic species (copper hydride and boryl copper). Furthermore, two types of alkenylboranes could be selectively synthesized by the choice of an appropriate ligand. Mechanistic studies confirmed that the protonation of a (Z)-σ-allyl copper species, which was isolated and structurally characterized by single-crystal X-ray diffraction, was a key step in these reactions. Besides allenes, this method is also applicable to the selective hydroboration of 1,3-diene derivatives to afford allylboranes and homoallylboranes. Copyright

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