1447846-66-3Relevant articles and documents
Intramolecular displacement of phenylselenone by a hydroxy group: Stereoselective synthesis of 2-substituted tetrahydrofurans
Minuti, Lucio,Barattucci, Anna,Bonaccorsi, Paola Maria,Di Gioia, Maria Luisa,Leggio, Antonella,Siciliano, Carlo,Temperini, Andrea
supporting information, p. 3906 - 3909 (2013/09/02)
An efficient and stereocontrolled synthesis of 2-substituted tetrahydrofurans has been achieved. The approach employs the asymmetric reduction of γ-phenylseleno ketones obtained by three different procedures that are peculiarly applied to the synthesis of such compounds. Finally, the intramolecular substitution of the phenylselenone residue by the oxygen atom of a hydroxy group gives the tetrahydrofuran ring.