144863-34-3

Basic information

• Product Name: 3-(2'-iodo-N-phenylsulphonylanilinyl)-2-chloromethylpropene
• Synonyms: 3-(2'-iodo-N-phenylsulphonylanilinyl)-2-chloromethylpropene
• CAS NO: 144863-34-3
• Molecular Weight: 447.724
• Mol File: 144863-34-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-(2'-iodo-N-phenylsulphonylanilinyl)-2-chloromethylpropene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2'-iodo-N-phenylsulphonylanilinyl)-2-chloromethylpropene(144863-34-3)
• EPA Substance Registry System: 3-(2'-iodo-N-phenylsulphonylanilinyl)-2-chloromethylpropene(144863-34-3)

Safety Data

• Hazardous Substances Data: 144863-34-3(Hazardous Substances Data)

Upstream product

• 1871-57-4 2-chloromethyl-3-chloroprop-1-ene 
• 54189-90-1 N-(2-iodophenyl)benzenesulfonamide 

Downstream Products

• 155391-79-0 N-(2-Iodo-phenyl)-N-[2-(4-oxo-4H-pyridin-1-ylmethyl)-allyl]-benzenesulfonamide 
• 155391-83-6 C₂₇H₂₅IN₂O₅S₂ 
• 128316-32-5 C₂₆H₂₈N₂O₄S₂ 
• 128316-33-6 N-(1-Benzenesulfonyl-3-methyl-2,3-dihydro-1H-indol-3-ylmethyl)-N-(2-methyl-allyl)-benzenesulfonamide 
• 145984-03-8 C₂₁H₁₈N₂O₃S 
• 309723-88-4 C₃₀H₃₆BrIN₂O₄S₂ 

Relevant articles and documents

Palladium catalysed tandem cyclisation-anion capture. Part 5: Cascade hydrostannylation-bis-cyclisation-intramolecular anion capture. Synthesis of bridged- and spiro-cyclic small and macrocyclic heterocycles

A series of O- and N-α,ω-enyne derivatives of 2-iodoarylethers and 2-iodoarylamides undergo palladium catalysed cascade hydrostannylation of the ω-alkyne moiety at 0-25°C followed by bis-cyclisation at 100-110°C terminating in intramolecular sp3-sp2 Stille coupling. These cascades provide a wide range of 5/6 and 5/12-17 membered bicyclic spiro- and bridged-ring heterocycles. (C) 2000 Elsevier Science Ltd.

Palladium Catalysed Tandem Cyclisation-Anion Capture Processes. Part 1. Background and Hydride Ion Capture by Alkyl- and ?-Allyl-Palladium Species.

A new, wide ranging, synthetically powerful, catalytic tandem cyclisation-anion capture process is proposed which depends on the rate of cyclisation of an organopalladium specifies (RPdX) onto a proximate alkene or diene being significantly faster than an