1448775-15-2

Basic information

• Product Name: C₁₁H₁₄O₂
• CAS NO: 1448775-15-2
• Molecular Weight: 178.231
• Mol File: 1448775-15-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₄O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₄O₂(1448775-15-2)
• EPA Substance Registry System: C₁₁H₁₄O₂(1448775-15-2)

Safety Data

• Hazardous Substances Data: 1448775-15-2(Hazardous Substances Data)

Upstream product

• 51015-29-3 6-methyl-3,4-dihydronaphthalen-1(2H)-one 

Downstream Products

• 1448774-89-7 2-(5-methoxypent-4-enyl)-4-methylphenol 
• 1448774-90-0 2-(5-methoxypent-4-enyl)-4-methylphenol 

Relevant articles and documents

Terminal olefins to chromans, isochromans, and pyrans via allylic C-H oxidation

The synthesis of chroman, isochroman, and pyran motifs has been accomplished via a combination of Pd(II)/bis-sulfoxide C-H activation and Lewis acid co-catalysis. A wide range of alcohols are found to be competent nucleophiles for the transformation under uniform conditions (catalyst, solvent, temperature). Mechanistic studies suggest that the reaction proceeds via initial C-H activation followed by a novel inner-sphere functionalization pathway. Consistent with this, the reaction shows reactivity trends orthogonal to those of traditional Pd(0)-catalyzed allylic substitutions.