1450594-40-7

Basic information

• Product Name: C₁₄H₂₂Si
• Synonyms: C₁₄H₂₂Si
• CAS NO: 1450594-40-7
• Molecular Weight: 218.414
• Mol File: 1450594-40-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₂Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₂Si(1450594-40-7)
• EPA Substance Registry System: C₁₄H₂₂Si(1450594-40-7)

Safety Data

• Hazardous Substances Data: 1450594-40-7(Hazardous Substances Data)

Upstream product

• 142-29-0 cyclopentene 
• 120578-34-9 (2,4,6-trimethylphenyl)silane 

Relevant articles and documents

Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

A cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with a variety of hydrosilanes under mild conditions and low catalyst loadings. DFT studies reveal the presence of two coupled catalytic cycles based on [(NPN)NiH]+and [(NPN)NiSiR3]+active species, with the latter being more efficient for producing the product. The preferred silyl-based catalysis is not due to a more facile insertion of alkene into the Ni-Si (vs.Ni-H) bond, but by consistent and efficient conversions of the hydride to the silyl complex.