145072-02-2

Basic information

• Product Name: 2-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoylamino]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester
• Synonyms: 2-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoylamino]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester
• CAS NO: 145072-02-2
• Molecular Weight: 422.524
• Mol File: 145072-02-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoylamino]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoylamino]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester(145072-02-2)
• EPA Substance Registry System: 2-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoylamino]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester(145072-02-2)

Safety Data

• Hazardous Substances Data: 145072-02-2(Hazardous Substances Data)

Upstream product

• 122181-86-6 1-carbomethoxy-2-amino-4,5,6,7-tetrahydro-2H-isoindole 
• 145071-98-3 (2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoic acid 
• 51555-65-8 cyclohexane-1,2-dicarbaldehyde 
• 149836-92-0 (S)-3-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-5-trimethylsilanyl-pent-4-ynoyl]-4-isopropyl-oxazolidin-2-one 
• 188911-98-0 1-(trimethylsilyl)-3(R*,S*)-methoxy-4(S)-(benzyloxy)-1-pentyne 
• 122181-84-4 1-carbomethoxy-2-phthalimido-4,5,6,7-tetrahydro-2H-isoindole 
• 122181-81-1 2-phthalimido-4,5,6,7-tetrahydro-2H-isoindole 
• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 15753-50-1 cis-1,2-cyclohexanedimethanol 

Downstream Products

• 145072-06-6 2-[(3R,4R)-3-((S)-1-Benzyloxy-ethyl)-4-methyl-2-methylene-5-oxo-pyrrolidin-1-yl]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester 

Relevant articles and documents

Studies on the Synthesis of Phytochrome and Related Tetrapyrroles. Dihydropyrromethenones by Photochemical Rearrangement of N-Pyrrolo Enamides

Dihydropyrromethenone 67b, a potential precursor for the synthesis of phytochrome 1, has been prepared in enantiomerically pure form beginning with N-aminopyrrole 64 and the acetylenic acid 62b. The key step involved a 3,5-sigmatropic rearrangement of N-pyrrolo enamide 66b.