1450734-61-8

Basic information

• Product Name: methyl 2,3-di-O-benzyl-4,6-di-O-(4-methoxybenzyl)-α-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-benzyl-4,6-di-O-(4-methoxybenzyl)-α-D-glucopyranoside
• CAS NO: 1450734-61-8
• Molecular Weight: 614.736
• Mol File: 1450734-61-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-benzyl-4,6-di-O-(4-methoxybenzyl)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-benzyl-4,6-di-O-(4-methoxybenzyl)-α-D-glucopyranoside(1450734-61-8)
• EPA Substance Registry System: methyl 2,3-di-O-benzyl-4,6-di-O-(4-methoxybenzyl)-α-D-glucopyranoside(1450734-61-8)

Safety Data

• Hazardous Substances Data: 1450734-61-8(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 67-56-1 methanol 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 105-13-5 4-Methoxybenzyl alcohol 
• 1450734-54-9 4-methoxybenzyl N-phenyl-2,2,2-trifluoroacetimidate 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

P-chlorobenzyl ether: A p-methoxybenzyl ether in disguise

In the chemistry of polyfunctionalized organic compounds, protecting groups that can undergo mild and selective cleavage while still being stable during the entire synthetic sequence are often required. In this work, we present a straightforward conversion of the robust p-chlorobenzyl ether into the more labile and well-described p-methoxybenzyl ether using palladium catalysis. This reaction was demonstrated to be high yielding and compatible with a wide range of functionalities, thereby providing a useful supplement to the conventional ether protecting groups.