145123-14-4

Basic information

• Product Name: 4-((E)-1-Ethyl-1-propyl-but-2-enyl)-morpholine
• CAS NO: 145123-14-4
• Molecular Weight: 211.348
• Mol File: 145123-14-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-((E)-1-Ethyl-1-propyl-but-2-enyl)-morpholine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-((E)-1-Ethyl-1-propyl-but-2-enyl)-morpholine(145123-14-4)
• EPA Substance Registry System: 4-((E)-1-Ethyl-1-propyl-but-2-enyl)-morpholine(145123-14-4)

Safety Data

• Hazardous Substances Data: 145123-14-4(Hazardous Substances Data)

Upstream product

• 2497-21-4 4-hexen-3-one 
• 106-94-5 propyl bromide 
• 540-54-5 1-Chloropropane 
• 110-91-8 morpholine 

Relevant articles and documents

3-Metallated enamines XI. Transmetallation of 3-Stannylated enamines - A new method to generate 1-aminoallyllithium compounds

The transmetallation of 3-stannylated enamines, 1-morpholino-3-(trialkylstannyl)cycloalk-1-enes and 3-morpholino-5-(tributylstannyl)hex-3-ene, with butyllithium is a new and general way to generate s1-aminoallyllithium compounds. Stabilization by aromatic substituents is not further necessarily as in the case of preparation by deprotonation and even the thermodynamically less stable exoamino derivatives are accessible. Therefore homoenolate-equivalents of cyclic ketones are made available. Thus, the corresponding 3-alkylated or 3-silylated cycloalkanones and alken-3-ones were prepared via the 1-morpholinoallyllithium compounds.