1453804-82-4

Basic information

• Product Name: C₁₉H₂₀ClNO
• Synonyms: C₁₉H₂₀ClNO
• CAS NO: 1453804-82-4
• Molecular Weight: 313.827
• Mol File: 1453804-82-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₉H₂₀ClNO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₂₀ClNO(1453804-82-4)
• EPA Substance Registry System: C₁₉H₂₀ClNO(1453804-82-4)

Safety Data

• Hazardous Substances Data: 1453804-82-4(Hazardous Substances Data)

Upstream product

• 197313-32-9 (E)-2-(6-chlorohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 574-66-3 Benzophenone oxime 

Downstream Products

• 1453804-95-9 C₁₉H₂₀ClNO 

Relevant articles and documents

Preparation of α-imino aldehydes by [1,3]-rearrangements of O-alkenyl oximes

The synthesis of α-imino aldehydes has been achieved through the thermal [1,3]-rearrangement of O-alkenyl benzophenone oximes. A copper-mediated C-O bond coupling between benzophenone oxime and alkenyl boronic acids provides facile access to the required O-alkenyl oximes and a Horner-Wadsworth-Emmons olefination can be applied to the α-imino aldehyde products to give γ-imino-α,β-unsaturated esters. The scope of the method is described and mechanistic experiments are discussed.