145483-68-7Relevant articles and documents
Coordinating Electron Transport Chains to an Electron Donor
Villegas, Carmen,Wolf, Maximilian,Joly, Damien,Delgado, Juan Luis,Guldi, Dirk M.,Martín, Nazario
, p. 5056 - 5059 (2015)
Two electron transport chains (2 and 3) featuring two fullerenes with different electron acceptor strengths have been synthesized, characterized, and coordinated to a light harvesting/electron donating zinc porphyrin. Electrochemical assays corroborate th
Boron ketoiminate-based conjugated polymers with tunable AIE behaviours and their applications for cell imaging
Dai, Chunhui,Yang, Dongliang,Zhang, Wenjie,Fu, Xiao,Chen, Qingmin,Zhu, Chengjian,Cheng, Yixiang,Wang, Lianhui
, p. 7030 - 7036 (2015)
Three new boron ketoiminate-based conjugated polymers P1, P2, and P3 were designed and synthesized through the Sonogashira coupling reaction of 4,6-bis(4-bromophenyl)-2,2-difluoro-3-phenyl-2H-1,3,2-oxazaborinin-3-ium-2-uide (M1) with 1,4-diethynyl-2,5-bis
White light emission from fluorene-EDOT and phenothiazine-hydroquinone based D-π-A conjugated systems in solution, gel and film forms
Anand, Vivek,Dhamodharan, Raghavachari
, p. 9741 - 9751 (2017)
Two conjugated D-π-A organic molecules, one fluorene-ethylene dioxythiophene (FL-E) based and another phenothiazine-hydroquinone (PT-Hq) based, were synthesized and observed to form 1-dimensional microstructures in the solid state. These two molecules whe
How Large Can We Build a Cyclic Assembly? Impact of Ring Size on Chelate Cooperativity in Noncovalent Macrocyclizations
Montoro-García, Carlos,Mayoral, María J.,Chamorro, Raquel,González-Rodríguez, David
, p. 15649 - 15653 (2017/12/02)
Self-assembled systems rely on intramolecular cooperative effects to control their growth and regulate their shape, thus yielding discrete, well-defined structures. However, as the size of the system increases, cooperative effects tend to dissipate. We analyze here this situation by studying a set of oligomers of different lengths capped with guanosine and cytidine nucleosides, which associate in cyclic tetramers by complementary Watson–Crick H-bonding interactions. As the monomer length increases, and thus the number of C(sp)–C(sp2) σ-bonds in the π-conjugated skeleton, the macrocycle stability decreases due to a notable reduction in effective molarity (EM), which has a clear entropic origin. We determined the relationship between EM or ΔS and the number of σ-bonds, which allowed us to predict the maximum monomer lengths at which cyclic species would still assemble quantitatively, or whether the cyclic species would not able to compete at all with linear oligomers over the whole concentration range.