145618-69-5Relevant articles and documents
Substituent Effects on 1,3-Dipolar Cycloadditions to Some 1,1-Diphenyl-2-Aza-1,3-Butadiene Derivatives.
Balsamini, Cesarino,Bedini, Annalida,Spadoni, Gilberto,Burdisso, Marina,Capelli, Anna Maria
, p. 3773 - 3784 (1994)
The reactivity and in particular the siteselectivity of electrocyclic additions to 1,1-diphenyl-2-aza-1,3-butadienes, substituted or not on the terminal carbon with methyl and phenyl, and with a 3-carbomethoxyl group, have been investigated with the
New α,β-Didehydroamino Acid Derivatives as Precursors in the Synthesis of 1-Aminocyclopropanecarboxylic Acids
Cativiela, Carlos,Diaz-de-Villegas, Maria D.,Jimenez, Ana I.
, p. 9157 - 9166 (2007/10/02)
The reaction of N-(diphenylmethylene)didehydroalanine methyl ester and N-didehydroalanine methyl ester with diazoalkanes or ylides gives the corresponding cyclopropane derivatives in high yields.The cis/trans ratio of these compounds was dependent on substrate, reagent and reaction temperature.From stereochemically homogeneous compounds the corresponding 1-aminocyclopropanecarboxylic acids were easily obtained by acid hydrolysis.