14562-09-5

Basic information

• Product Name: 2-PHENYL-2,4,6-CYCLOHEPTATRIEN-1-ONE
• Synonyms: 2-PHENYL-2,4,6-CYCLOHEPTATRIEN-1-ONE;2-Phenyltropone
• CAS NO: 14562-09-5
• Molecular Formula: C₁₃H₁₀O
• Molecular Weight: 182.2179
• Mol File: 14562-09-5.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-PHENYL-2,4,6-CYCLOHEPTATRIEN-1-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-PHENYL-2,4,6-CYCLOHEPTATRIEN-1-ONE(14562-09-5)
• EPA Substance Registry System: 2-PHENYL-2,4,6-CYCLOHEPTATRIEN-1-ONE(14562-09-5)

Safety Data

• Hazardous Substances Data: 14562-09-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 75, p. 2387, 1953 DOI: 10.1021/ja01106a031

Upstream product

• 2161-40-2 2-methoxytropone 
• 60-29-7 diethyl ether 
• 533-75-5 2-hydroxy-2,4,6-cycloheptatrien-1-one 
• 591-51-5 phenyllithium 
• 539-80-0 Tropone 
• 71-43-2 benzene 
• 1714-38-1 7-methoxy-1,3,5-cycloheptatriene 
• 38768-08-0 2-(tosyloxy)tropone 
• 960-16-7 tributylphenylstannane 
• 700-69-6 6-hydroxy-7-oxo-cyclohepta-1,3,5-trienecarbonitrile 
• 92151-32-1 2-cyano-7-phenyltropone 
• 90128-00-0 1-methoxy-2-phenylcycloheptatriene 
• 133436-04-1 5-(diethylamino)-7-phenylbicyclo<3.2.0>hept-2-en-6-one 
• 133521-23-0 5-(diethylamino)-7-phenylbicyclo<3.2.0>hept-2-en-6-one hydrochloride 

Downstream Products

• 141023-23-6 8-ethylidene-7-methyl-1-phenylbicyclo<4.3.1>decan-10-one 
• 141023-22-5 7,9-dimethyl-8-methylene-1-phenylbicyclo<4.3.1>decan-10-one 
• 128742-64-3 2-phenyltropothione 
• 142073-80-1 8-cyano-8-(4-nitrophenyl)-3-phenylheptafulvene 
• 142073-79-8 E-8-cyano-8-(4-nitrophenyl)-2-phenylheptafulvene 
• 1154-38-7 2,7-diphenyl-cycloheptatrienone 
• 40394-16-9 (E)-3-(6-Ethoxy-biphenyl-3-yl)-1-(4-nitro-phenyl)-propenone 
• 40394-17-0 (E)-3-(2-Ethoxy-biphenyl-3-yl)-1-(4-nitro-phenyl)-propenone 
• 855390-40-8 2,4,5-tribromo-7-phenyl-cyclohepta-2,6-dienone 
• 856183-85-2 4,5,6,7-tetrabromo-2-phenyl-cyclohept-2-enone 
• 16446-76-7 7-amino-2-phenyltropone 
• 100727-09-1 2-phenyl-cycloheptatrienone oxime 
• 14996-78-2 2-phenylcycloheptanone 
• 126953-85-3 11-Phenyl-tricyclo[7.3.2.0^2,8]tetradeca-3,5,7,11,13-pentaen-10-one 

Relevant articles and documents

Regio- and diastereoselective stepwise [8 + 3]-cycloaddition reaction between tropone derivatives and donor-acceptor cyclopropanes

A novel SnCl4-catalyzed [8 + 3]-cycloaddition reaction between tropone derivatives and donor-acceptor aminocyclopropanes is described. The process leads to the formation of amino-substituted tetrahydrocyclohepta[b] pyrans with complete regio- and diastereoselectivity. Density functional theory calculations suggest that the cycloaddition occurs stepwise through an aromatic zwitterionic intermediate.

Abnormal Nucleophilic Substitution on Methoxytropone Derivatives: Steric Strategy to Synthesize 5-Substituted Azulenes

Azulene is a non-alternant non-benzenoid aromatic system, and in turn, it possesses unusual photophysical properties. Azulene-based conjugated systems have received increasing interest in recent years as optoelectronic materials. Despite the routes availa

Preparation and Palladium-Catalyzed Cross-Coupling of Aryl Triethylammonium Bis(catechol) Silicates with Aryl Triflates

Pentavalent aryl and heteroaryl bis(catechol) silicates undergo palladium-catalyzed cross-coupling with aryl and heteroaryl triflates in the presence of a fluoride source in excellent yields. These solid, air-stable bis(catechol) silicates are prepared from a high-yielding displacement reaction between catechol and an aryl siloxane in the presence of an amine base. The cross-coupling reaction is tolerant of a wide range of electron-donating and electron-withdrawing groups. Several examples of di-ortho-substituted triflates are successfully coupled with these reagents.