146041-79-4

Basic information

• Product Name: 9-Azabicyclo[6.1.0]nonane, 9-[(4-methylphenyl)sulfonyl]-, (1R,8S)-rel-
• CAS NO: 146041-79-4
• Molecular Formula: C15H21NO2S
• Molecular Weight: 279.403
• Mol File: 146041-79-4.mol
• Article Data: 51

Chemical Properties

• CAS DataBase Reference: 9-Azabicyclo[6.1.0]nonane, 9-[(4-methylphenyl)sulfonyl]-, (1R,8S)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Azabicyclo[6.1.0]nonane, 9-[(4-methylphenyl)sulfonyl]-, (1R,8S)-rel-(146041-79-4)
• EPA Substance Registry System: 9-Azabicyclo[6.1.0]nonane, 9-[(4-methylphenyl)sulfonyl]-, (1R,8S)-rel-(146041-79-4)

Safety Data

• Hazardous Substances Data: 146041-79-4(Hazardous Substances Data)

Upstream product

• 931-88-4 cis-Cyclooctene 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 71996-32-2 N-(5λ⁴-dibenzo[b,d]thiophen-5-ylidene)-4-methylbenzenesulfonamide 
• 931-88-4 1,2-cyclooctene 
• 127-65-1 chloroamine-T 
• 1338062-05-7 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 41085-71-6 bromamine T 
• 1058-14-6 N-p-tolylsulfonylphosphine imide 
• 144-86-5 N-chloro-4-methylbenzenesulfonamide 
• 292-64-8 Cyclooctan 
• 76152-15-3 N-iodo-N-potassio-p-toluenesulphonamide 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 
• 473-34-7 N,N-dichloro-p-toluenesulfonamide 

Downstream Products

• 118157-82-7 (Z)-N-(cyclooct-2-en-1-yl)-4-methylbenzenesulfonamide 
• 197145-72-5 N-(2-chlorocyclooctyl)-4-methylbenzenesulfonamide 
• 1257216-50-4 C₂₁H₂₅NO₃S 

Relevant articles and documents

Palladium-catalyzed aziridination of alkenes using N,N-dichloro-p-toluenesulfonamide as nitrogen source

N,N-Dichloro-p-toluenesulfonamide (TsNCl2) was found to be an efficient nitrogen source for the aziridination of unfunctionalized alkenes using palladium catalysts. Among the palladium salts, palladium acetate was the most effective catalyst for this reaction. A variety of alkenes were reacted at room temperature with TsNCl2 to form the desired aziridines in moderate to good yields. This method can complement our previous protocol which is limited to the use of electron-deficient α,β-unsaturated alkenes.

Efficient copper-catalyzed benzylic amidation with anhydrous chloramine-T

Benzylic hydrocarbons are selectively converted to the corresponding sulfonamides by the [Cu(CH3CN)4]PF6-catalyzed reaction with anhydrous TolSO2NNaCl (chloramine-T). Under the same conditions, representative ethers are also α-amidated; olefins produce allyl sulfonamides, aziridines, and/or β-chloro sulfonamides.

Formation of an Iron(III) Porphyrin Complex with a Nitrene Moiety Inserted into a Fe-N Bond during Alkene Aziridination by benzene Catalyzed by Iron(III) Porphyrins

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Heterogeneous Olefin Aziridination Reactions Catalyzed by Polymer-Bound Tris(triazolyl)methane Copper Complexes

Efficient olefin aziridination has been achieved with a tris(triazolyl)methane copper catalyst supported onto polystyrene. Aryl, alkyl and methoxycarbonyl-substituted olefins are converted into N-tosylaziridines in good to high yields. The solid catalyst is readily separated by filtration and recycled, allowing its reuse with no significant loss of the catalytic activity.

An Electron-Poor Dioxa-[2.1.1]-(2,6)-pyridinophane Ligand and Its Application in Cu-Catalyzed Olefin Aziridination

A novel macrocyclic 1,7-dioxa-[2.1.1]-(2,6)-pyridinophane ligand has been synthesized and crystallographically characterized. Two derived metal complexes, dichloropalladium(II) and chlorocopper(I), were prepared. In the palladium(II) complex LPdCl2/

Copper-Catalyzed Aziridination with Redox-Active Ligands: Molecular Spin Catalysis

Small-molecule catalysts as mimics of biological systems illustrate the chemists’ attempts at emulating the tantalizing abilities displayed by nature's metalloenzymes. Among these innate behaviors, spin multistate reactivity is used by biological systems as it offers thermodynamic leverage towards challenging chemical reactivity but this concept is difficult to translate into the realm of synthetic organometallic catalysis. Here, we report a rare example of molecular spin catalysis involving multistate reactivity in a small-molecule biomimetic copper catalyst applied to aziridination. This behavior is supported by spin state flexibility enabled by the redox-active ligand.