14670-41-8

Basic information

• Product Name: Benzene, 1-chloro-4-(1-pentenyl)-
• CAS NO: 14670-41-8
• Molecular Formula: C11H13Cl
• Molecular Weight: 180.677
• Mol File: 14670-41-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(1-pentenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(1-pentenyl)-(14670-41-8)
• EPA Substance Registry System: Benzene, 1-chloro-4-(1-pentenyl)-(14670-41-8)

Safety Data

• Hazardous Substances Data: 14670-41-8(Hazardous Substances Data)

Upstream product

• 1009-14-9 phenyl butyl ketone 
• 587-04-2 m-Chlorobenzaldehyde 
• 104-88-1 4-chlorobenzaldehyde 
• 672263-60-4 1-chloro-4-(pent-1-yn-1-yl)benzene 
• 1779-51-7 n-butyl(triphenyl)phosphonium bromide 
• 72435-61-1 1-(4-chlorobenzyl)-1H-benzo[d][1,2,3]triazole 
• 89121-80-2 erythro-(1-hydroxy-1-phenyl-2-pentyl)triphenylphosphonium bromide 
• 17369-07-2 2-(butylsulfonyl)benzo[d]thiazole 

Relevant articles and documents

Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

A new efficient method for the synthesis of a high ratio of E -alkenes from E / Z mixtures of alkenes with B 2pin 2in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.

Light Mediated Preparation of Palladium Nanoparticles as Catalysts for Alkyne cis-Semihydrogenation

A bisacylphosphine oxide photoinitiator was used for the light mediated preparation of palladium nanoparticles (PdNPs) with a small diameter of 2.8 nm. All starting materials are commercially available, and PdNP synthesis is experimentally very easy to conduct. The PdNP-hybrid material was applied as catalyst for the semihydrogenation of various internal alkynes to provide the corresponding alkenes in excellent yields (up to 99%) and Z-selectivities (Z/E ratios up to 99/1).

Trans-Selective Olefination of Carbonyl Compounds by Low-Valent Titanium-Mediated Dehydroxybenzotriazolylation

Lithiation with n-butyllithium of a variety of benzotriazole derivatives 1a-f and 5a-d, all containing a proton α to the benzotriazolyl moiety, gave anions which underwent addition to aliphatic, aromatic, and α,β-unsaturated aldehydes and cyclic and acyclic ketones. The resultant N-(β-hydroxyalkyl)benzotriazole derivatives 3a-m, 6a-g, 9a-d, and 10a were dehydroxybenzotriazolylated when treated with low-valent titanium to give alkenes 4a-m, dienes 7a- j, and triene 11a, with selectivity for the trans isomers without separation of diastereoisomeric intermediates. This method offers an alternative to the three most frequently used methods for the formation of alkenes from carbonyl compounds-the Wittig, Peterson, and Julia reactions-especially in the formation of tri- and tetrasubstituted alkenes.