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1470372-59-8

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  • dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II)

    Cas No: 1470372-59-8

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  • Hebei yanxi chemical co.,LTD.
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  • Factory Price OLED 99% 1470372-59-8 Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Manufacturer

    Cas No: 1470372-59-8

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  • Xi'an Xszo Chem Co., Ltd.
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  • [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]-palladium(II) methanesulfonate

    Cas No: 1470372-59-8

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1470372-59-8 Usage

Reaction

Catalyst used in the regioselective synthesis of benzimidazolones via cascade C-N coupling of monosubstituted ureas. Catalyst used in a mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow .applications to the synthesis of functionalized heterocycles.

Uses

BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.It may be used in the synthesis of following compounds: [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.[Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.[Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

General Description

BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Check Digit Verification of cas no

The CAS Registry Mumber 1470372-59-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,7,0,3,7 and 2 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1470372-59:
(9*1)+(8*4)+(7*7)+(6*0)+(5*3)+(4*7)+(3*2)+(2*5)+(1*9)=158
158 % 10 = 8
So 1470372-59-8 is a valid CAS Registry Number.

1470372-59-8 Well-known Company Product Price

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  • Alfa Aesar

  • (47250)  BrettPhos Palladacycle 3rd Generation, 98%   

  • 1470372-59-8

  • 250mg

  • 1232.0CNY

  • Detail
  • Alfa Aesar

  • (47250)  BrettPhos Palladacycle 3rd Generation, 98%   

  • 1470372-59-8

  • 1g

  • 4284.0CNY

  • Detail
  • Alfa Aesar

  • (47250)  BrettPhos Palladacycle 3rd Generation, 98%   

  • 1470372-59-8

  • 5g

  • 15400.0CNY

  • Detail

1470372-59-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name BrettPhos-G3-Pd

1.2 Other means of identification

Product number -
Other names METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1470372-59-8 SDS

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