147730-52-7

Basic information

• Product Name: (+/-)-loliolide
• CAS NO: 147730-52-7
• Molecular Weight: 196.246
• Mol File: 147730-52-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (+/-)-loliolide(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-loliolide(147730-52-7)
• EPA Substance Registry System: (+/-)-loliolide(147730-52-7)

Safety Data

• Hazardous Substances Data: 147730-52-7(Hazardous Substances Data)

Upstream product

• 147804-31-7 (6S,7R,7aS)-7-bromo-6-hydroxy-4,4,7a-trimethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)-one 
• 509095-03-8 6-(tert-butyl-dimethyl-silanyloxy)-4,4,7a-trimethyl-5,6,7,7a-tetrahydro-4H-benzofuran-2-one 
• 214335-71-4 (-)-[(S)-4-(tert-butyldimethylsilyloxy)-2,6,6-trimethylcyclohex-1-enyl]methanol 
• 439859-70-8 (-)-(1S,4S,6R)-4-(tert-butyldimethylsilyloxy)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-carbaldehyde 
• 439859-71-9 (-)-[(1R,4S,6R)-4-(tert-butyldimethylsilyloxy)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]heptan-1-yl]methanol 
• 1027310-67-3 (6S,7aR)-6-(tert-Butyl-dimethyl-silanyloxy)-4,4,7a-trimethyl-2,4,5,6,7,7a-hexahydro-benzofuran-2-ol 
• 147641-88-1 (6R,7S,7aR)-7-bromo-6-hydroxy-4,4,7a-trimethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)-one 
• 93676-55-2 hexahydro-3aα,4,5,6,7,7aα (3H) hydroxy-6 phenylseleno-3 trimethyl-4,4,7α benzofurannone-2 
• 1133-01-3 hexahydro-3aα,4,5,6,7,7aα (3H) hydroxy-6 trimethyl-4,4,7α benzofurannone-2 
• 79693-70-2 (3aR,7aR)-4,4,7a-Trimethyl-3a,4,7,7a-tetrahydro-3H-benzofuran-2-one 
• 147641-90-5 (3aS,7S,7aS)-7-iodo-4,4,7a-trimethyl-3a,4,5,6,7,7a-hexahydrobenzofuran-2(3H)-one 
• 147730-51-6 (3aS,7aR)-4,4,7a-trimethyl-3a,4,5,7a-tetrahydrobenzofuran-2(3H)-one 
• 147641-89-2 (S)-(2,6,6-trimethylcyclohex-2-enyl)acetic acid 
• 79499-04-0 (3aS,5S,7aS)-4,4,7a-Trimethyl-5-phenylselanyl-hexahydro-benzofuran-2-one 

Relevant articles and documents

Synthesis of loliolide, actinidiolide, dihydroactinidiolide, and aeginetolide via cerium enolate chemistry

(Chemical Equation Presented) Loliolide, aeginetolide, actinidiolide, and dihydroactinidiolide were synthesized in racemic form from a single common intermediate, prepared through the 1,2 addition of the cerium enolate of ethyl acetate to 2,6,6-trimethylcylohexenone.

Carotenoids and Degraded Carotenoids, VIII. Synthesis of (+)-Dihydroactinidiolide, (+)- and (-)-Actinidiolide, (+)- and (-)-Loliolide as well as (+)- and (-)-Epiloliolide

Enantiomerically pure (S)-2,4,4-trimethyl-2-cyclohexen-1-ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)-dihydroactinidiolide (5), (S)-actinidiolide (9), (6S,7aR)-loliolide (11) and (6S,7aS)-epiloliolide (12). (R)-Actinidioli

SYNTHESE DU (+/-) LOLIOLIDE PAR POLYCYCLISATION DE L'ACIDE HOMOGERANIQUE.

A new synthesis of (+/-) loliolide was achieved from pure homogeranic acid in a stereospecific fashion.The intermediate ethylenic lactone 6 was converted to the racemate of lol