147776-85-0

Basic information

• Product Name: (E)-1,1,1,2,2,3,3,4,4-nonafluoro-7-phenylhept-6-en-5-one
• CAS NO: 147776-85-0
• Molecular Weight: 350.184
• Mol File: 147776-85-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-1,1,1,2,2,3,3,4,4-nonafluoro-7-phenylhept-6-en-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,1,1,2,2,3,3,4,4-nonafluoro-7-phenylhept-6-en-5-one(147776-85-0)
• EPA Substance Registry System: (E)-1,1,1,2,2,3,3,4,4-nonafluoro-7-phenylhept-6-en-5-one(147776-85-0)

Safety Data

• Hazardous Substances Data: 147776-85-0(Hazardous Substances Data)

Upstream product

• 423-39-2 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane 
• 4192-77-2 ethyl cinnamate 
• 286858-47-7 (E)-5-ethoxy-1,1,1,2,2,3,3,4,4-nonafluoro-6-(phenylseleno)hex-5-ene 
• 424-36-2 2,2,3,3,4,4,5,5,5-nonafluoropentanoic acid ethyl ester 
• 286858-74-0 (Z)-5-ethoxy-1,1,1,2,2,3,3,4,4-nonafluoro-7-phenylhept-5-en-7-ol 
• 103-26-4 Methyl cinnamate 

Downstream Products

• 90550-17-7 4,4,5,5,6,6,7,7,7-Nonafluoro-1-phenyl-heptan-3-one 
• 90550-20-2 (S)-4,4,5,5,6,6,7,7,7-Nonafluoro-1-phenyl-heptan-3-ol 
• 90550-20-2 (R)-4,4,5,5,6,6,7,7,7-Nonafluoro-1-phenyl-heptan-3-ol 

Relevant articles and documents

A new entry for the oxidation of fluoroalkyl-substituted methanol derivatives: Scope and limitation of the organoiodine(V) reagent-catalyzed oxidation

Oxidation of various fluoroalkyl-substituted methanol derivatives under the influence of a catalytic amount of sodium 2-iodobenzenesulfonate and Oxone in CH3CN or CH3NO2 was investigated in detail. The efficiency of the newly developed oxidation was also evaluated by comparison to other oxidations, such as Dess-Martin, PDC, and Swern oxidation.

A new α-seleno- or nonselenoperfluoroacyl olefination of aldehydes and ketones using β-ethoxy-β-perfluoroalkyl vinylic selenides

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An Efficient Synthesis of Perfluoroalkyl Ketones Using Perfluoroalkyllithiums

Perfluoroalkylation of esters with perfluoroalkyllithiums occurs smoothly in ether at -78 deg C, giving the corresponding perfluoroalkyl ketones in good yields.