147848-85-9

Basic information

• Product Name: 3-{2-[2-(2,2-Bis-isopropoxycarbonyl-1-methoxy-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-2-isopropoxycarbonyl-3-methoxy-acrylic acid isopropyl ester
• Synonyms: 3-{2-[2-(2,2-Bis-isopropoxycarbonyl-1-methoxy-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-2-isopropoxycarbonyl-3-methoxy-acrylic acid isopropyl ester
• CAS NO: 147848-85-9
• Molecular Weight: 642.877
• Mol File: 147848-85-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-{2-[2-(2,2-Bis-isopropoxycarbonyl-1-methoxy-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-2-isopropoxycarbonyl-3-methoxy-acrylic acid isopropyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-{2-[2-(2,2-Bis-isopropoxycarbonyl-1-methoxy-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-2-isopropoxycarbonyl-3-methoxy-acrylic acid isopropyl ester(147848-85-9)
• EPA Substance Registry System: 3-{2-[2-(2,2-Bis-isopropoxycarbonyl-1-methoxy-vinylsulfanyl)-ethyldisulfanyl]-ethylsulfanyl}-2-isopropoxycarbonyl-3-methoxy-acrylic acid isopropyl ester(147848-85-9)

Safety Data

• Hazardous Substances Data: 147848-85-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 52303-69-2 Diisopropyl 1,3-dithiolan-2-ylidenemalonate 1-oxide 
• 147848-84-8 C₂₆H₄₂O₁₁S₄ 

Downstream Products

• 50512-35-1 isoprothiolane 
• 52303-69-2 Diisopropyl 1,3-dithiolan-2-ylidenemalonate 1-oxide 

Relevant articles and documents

Chemical Reactivity of Oxidation Products of the Dithiolanylidenemalonate Fungicide, Isoprothiolane

Diisopropyl dithiolanylidenemalonate (isoprothiolane) was oxidized with m-chloroperbenzoic acid to give a monosulfoxide, disulfoxide, and disulfone.The monosulfide was subjected to addition reactions with such nucleophiles as methanol, thiols, and amines at the thioacetal carbon to open the dithiolane ring, affording a thiosulfinate, sulfinate and disulfide.The presence of a small amount of sodium carbonate accelerated the reactions and, moreover, reformed isoprothiolane from the ring-opened addition products.The further oxidation products were transformed into dithianes by reacting with nucleophiles.Isoprothiolane monosulfoxide inhibited alcohol dehydrogenase, an SH enzyme.