14996-70-4Relevant articles and documents
CuCl-catalyzed Oxidative Coupling Reaction of Secondary Amines with Molecular Oxygen in Pyridine
Kajimoto, Tsunesuke,Takahashi, Hidetaka,Tsuji, Jiro
, p. 3673 - 3674 (1982)
Oxidation of diphenylamine with molecular oxygen in the presence of CuCl in pyridine at room temperature to give tetraphenylhydrazine in a high yield was achieved by selecting suitable reaction conditions.N-methylaniline was also oxidized to give N,N'-dim
Method for realizing N-N coupling of secondary arylamine by utilizing electrochemical reaction
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Paragraph 0044-0046; 0053-0068, (2021/04/14)
The invention relates to the technical field of organic synthesis, and discloses a method for realizing the N-N coupling of secondary arylamine by utilizing electrochemical reaction, i.e., in a deviceprovided with an anode and a cathode, an Nmethylaniline
Cu(I) catalyzed dehydrogenative homo coupling of aromatic amines under simple and mild reaction conditions
Reddy, C.B. Rajashekhar,Reddy, Sabbasani Rajasekhara,Naidu, Shivaji
, p. 50 - 54 (2014/08/05)
An efficient protocol for the synthesis of a variety of azobenzenes and hydrazines from aromatic amines under mild reaction conditions is developed using Cu(I) catalyst. The copper cataylst used in this study comprises of CuBr, DMAP and AIBN. The plausible proposed mechanism for this dehydrogenative homo coupling of aromatic amines is depicted.