150272-41-6

Basic information

• Product Name: Benzenepropanol, a-methyl-, benzoate
• CAS NO: 150272-41-6
• Molecular Formula: C17H18O2
• Molecular Weight: 254.329
• Mol File: 150272-41-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenepropanol, a-methyl-, benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanol, a-methyl-, benzoate(150272-41-6)
• EPA Substance Registry System: Benzenepropanol, a-methyl-, benzoate(150272-41-6)

Safety Data

• Hazardous Substances Data: 150272-41-6(Hazardous Substances Data)

Upstream product

• 532-32-1 sodium benzoate 
• 2344-70-9 1-phenyl-3-butanol 
• 434935-69-0 2-methyl-6-nitrobenzoic anhydride 
• 65-85-0 benzoic acid 
• 343228-65-9 C₁₄H₇Cl₃O₃ 
• 98-88-4 benzoyl chloride 
• 2344-70-9 (+)-(S)-4-phenylbutan-2-ol 
• 59456-20-1 (rac)-(3-iodobutyl)benzeze 
• 611239-90-8 C₁₇H₂₈N₂O 
• 113761-32-3 4-phenyl-2-butyl 1-imidazolecarboxylate 
• 100-59-4 phenylmagnesium chloride 
• 582-25-2 Potassium benzoate 
• 155929-90-1 3,5-bis(trifluoromethyl)benzoic anhydride 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 2344-70-9 1-phenyl-3-butanol 

Relevant articles and documents

Two-Step Protocol for Iodotrimethylsilane-Mediated Deoxy-Functionalization of Alcohols

We have developed a two-step protocol for iodotrimethylsilane-mediated deoxy-functionalization of primary and secondary alcohols to afford products containing a C?N, C?S, or C?O bond. In the first step the alcohol undergoes iodination with iodotrimethylsilane, and in the second, the iodine atom is replaced by a N, S, or O nucleophile. Compared with traditional Mitsunobu reaction, non-acidic pre-nucleophiles can be used, and the reaction proceeds with retention of configuration. This operationally simple, highly efficient protocol can be used for some natural products and small-molecule drugs containing hydroxy-group.

METHOD OF CONVERTING ALCOHOL TO HALIDE

The present invention relates to a method of converting an alcohol into a corresponding halide. This method comprises reacting the alcohol with an optionally substituted aromatic carboxylic acid halide in presence of an N-substituted formamide to replace a hydroxyl group of the alcohol by a halogen atom. The present invention also relates to a method of converting an alcohol into a corresponding substitution product. The second method comprises: (a) performing the method of the invention of converting an alcohol into the corresponding halide; and (b) reacting the corresponding halide with a nucleophile to convert the halide into the nucleophilic substitution product.

Microwave-assisted ester formation using O-alkylisoureas: A convenient method for the synthesis of esters with inversion of configuration

(Chemical Equation Presented) The formation of carboxylic esters via reaction of carboxylic acids with O-alkylisoureas proceeds in excellent yields with very short reaction times when conducted in a monomode microwave synthesizer. Efficient processes were