15252-45-6Relevant articles and documents
"Click" chemistry by microcontact printing
Rozkiewicz, Dorota I.,Janczewski, Dominik,Verboom, Willem,Ravoo, Bart Jan,Reinhoudt, David N.
, p. 5292 - 5296 (2006)
(Chemical Equation Presented) Print and click: "Click" chemistry can be efficiently combined with microcontact printing. Synthesis in the nanoscale confinement between an elastomeric stamp and a reactive substrate leads to the desired product within a short time, without a catalyst, and under ambient conditions. As a result, 1-octadecyne could be printed onto an azido-terminated, self-assembled monolayer on a silicon oxide substrate (see scheme).
Azerocyclic compounds and their uses
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Paragraph 0381-0386, (2022/01/20)
The present invention proposes a nitrogen heterocyclic compound and its use, in particular, the present invention proposes a new compound that effectively inhibits ATX, which is a compound shown in the formula below, or a tautomer of the compound shown be
A Commercially Available and User-Friendly Catalyst for Hydroamination Reactions under Technical Conditions
Zelenay, Benjamin,Munton, Peter,Tian, Xiaojie,Díez-González, Silvia
supporting information, p. 4725 - 4730 (2019/08/01)
The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalyst was also found active in intermolecular aza-Michael reactions.
Synthesis and solid-state polymerization of a macrocyclic compound with two butadiyne units
Kikuchi, Kohei,Tatewaki, Yoko,Okada, Shuji
, p. 387 - 394 (2017/06/14)
A macrocyclic compound 1 with two butadiyne and four dodecyloxy-substituted benzamide moieties was successfully synthesized, and its ring structure was confirmed by the MALDI-TOF mass spectra and the 1HNMR spectra. Compound 1 showed two modifications depending on solvent for the solidification. Characteristic excitonic absorption bands of polydiacetylene were observed at around 500 nm for one of the modifications after UV irradiation. Quantitative conversion of butadiyne moieties to the corresponding polydiacetylene structure was confirmed by the Raman spectra.