152757-22-7

Basic information

• Product Name: Acetic acid, (phenylsulfonyl)-, phenylmethyl ester
• CAS NO: 152757-22-7
• Molecular Formula: C15H14O4S
• Molecular Weight: 290.34
• Mol File: 152757-22-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Acetic acid, (phenylsulfonyl)-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, (phenylsulfonyl)-, phenylmethyl ester(152757-22-7)
• EPA Substance Registry System: Acetic acid, (phenylsulfonyl)-, phenylmethyl ester(152757-22-7)

Safety Data

• Hazardous Substances Data: 152757-22-7(Hazardous Substances Data)

Upstream product

• 156051-47-7 benzyl 2-(phenylthio)acetate 
• 3112-85-4 methylphenylsulfonate 
• 153870-09-8 (S)-1-(benzyloxycarbonyl)-5-[(tert-butyldimethylsilyl)oxymethyl]-2-pyrrolidinone 
• 81470-51-1 tert-butyl N-benzyloxycarbonyl-L-pyroglutamate 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 5437-45-6 Benzyl bromoacetate 
• 873-55-2 sodium benzenesulfonate 
• 52267-51-3 benzyl diazoacetate 
• 100-51-6 benzyl alcohol 

Downstream Products

• 100-51-6 benzyl alcohol 

Relevant articles and documents

Cross coupling of sulfonyl radicals with silver-based carbenes: A simple approach to β-carbonyl arylsulfones

A coupling reaction between sulfonyl radicals and silver-based carbenes has been well established. This simple radical-carbene coupling (RCC) process provided an efficient approach to a variety of β-carbonyl arylsulfones from sodium arylsulfinates and diazo compounds, and was characterized by wide substrate scope, easy scale-up, simple manipulation, accessible starting materials, and mild reaction conditions.

MANUFACTURING METHOD OF COMPOUND HAVING SULFONYL GROUP

The present invention relates to a method for manufacturing a compound having a sulfonyl group, which includes a step for reacting thiosulfonates in a solvent comprising nucleophilic bases with an electrophilic agent. Accordingly, the present invention can manufacture the compound having the sulfonyl group with a variety of structures with high efficiency and high yield through more simplified processes than conventional methods.COPYRIGHT KIPO 2018

New Diastereoselective Route to 2-Substituted cis-(2S,5S)- and trans-(2S,5R)-5-Alkylpyrrolidines as Indolizidine and Pyrrolizidine Scaffolds

A new and short stereoselective route to the synthesis of enantiopure cis-2,5-disubstituted pyrrolidines as indolizidine or pyrrolizidine scaffolds has been developed. The method, which uses (S)-pyroglutamic acid as a chiral starting material, is based on the ring opening of N-protected 7-lactams by alkyl phenyl sulfone carbanions, followed by desulfonylation and reductive amination of alkyl 7-amino ketones. The diastereoselectivity depends on the substitution of the starting γ-lactams, and on the alkyl group of the phenyl sulfone. Total cis diastereoselectivity was observed in the formation of tert-butyl 5-alkylprolinates. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.