153141-25-4Relevant articles and documents
Asymmetric syn-Dihydroxylation of β-Substituted (2R)-N-(α,β-Enoyl)bornane-10,2-sultams
Raczko, Jerzy,Achmatowicz, Michael,Jezewski, Artur,Chapuis, Christian,Urbanczyk-Lipkowska, Zofia,Jurczak, Janusz
, p. 1264 - 1276 (1998)
Variously β-substituted (2R)-N-[(E)-α,β-enoyl]bornane-10,2-sultams were oxidized with OsO4/4-methylmorpholine 4-oxide in a highly stereoselective manner. In all cases, the attack occurred on the C(α)-re face. The absolute configurations of all
Diastereoselective alkyl Grignard 1,4-additions to para-substituted (2R)-N-cinnamoylbornane-10,2-sultam derivatives: Influence of N-atom pyramidalization
Piatek, Anna M.,Sadowska, Agnieszka,Chapuis, Christian,Jurczak, Janusz
experimental part, p. 2141 - 2167 (2012/01/31)
Several typical 13C-NMR displacements (of C=O, C(α), C(β), and Cipso), as well as conformational or energy properties (S-N-C=O dihedral angle, ΔE syn/anti; HOMO/LUMO) could be correlated with the electronic parameters of p-substitute