153531-52-3

Basic information

• Product Name: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[4-methyl-
• CAS NO: 153531-52-3
• Molecular Formula: C26H20N2
• Molecular Weight: 360.458
• Mol File: 153531-52-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[4-methyl-(153531-52-3)
• EPA Substance Registry System: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[4-methyl-(153531-52-3)

Safety Data

• Hazardous Substances Data: 153531-52-3(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 82-86-0 acenaphthene quinone 
• 153531-54-5 N,N'-bis(4-methoxyphenylimino)acenaphthene 
• 155889-93-3 {bis(p-Me-phenylimino)acenaphthene}(tetracyanoethylene)palladium⁽⁰⁾ 
• 155889-89-7 (1,2-bis[N-(4-methylphenyl)imino-N]-acenaphthene)(η(2)-maleic anhydride)palladium(0) 
• 153531-53-4 1,4-(4-chloro)phenyl-2,4-naphthalenediazabutadiene 
• 444798-21-4 α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate 
• 24220-43-7 N,N'-bis(phenylimino)acenaphthene 
• 674323-18-3 (C₁₂H₆N₂(C₆H₄CH₃)2)Pd(CH₂C(CH₃)CH₂)⁽¹⁺⁾*PF₆^(1-)=(C₁₂H₆N₂(C₆H₄CH₃)2)Pd(CH₂C(CH₃)CH₂)PF₆ 
• 226071-20-1 bis(4-trifluoromethylphenyl)acenaphthenequinonediimine 
• 444798-19-0 bis(3-trifluoromethylphenyl)acenaphthenequinonediimine 
• 156398-85-5 {(bis(p-tolylimino)acenaphthene)zinc chloride} 

Downstream Products

• 155889-89-7 (1,2-bis[N-(4-methylphenyl)imino-N]-acenaphthene)(η(2)-maleic anhydride)palladium(0) 
• 135719-29-8 {bis(p-Me-phenylimino)acenaphthene}(dimethyl fumarate)palladium⁽⁰⁾ 
• 196811-10-6 2,3,4,5-tetrakis(carbomethoxy)palladacyclopentadiene(bis(p-tolylimino)acenaphthene) 
• 184959-78-2 PtCl₂(bis(p-Tol-imino)acenaphthene) 
• 444798-21-4 α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate 
• 185405-97-4 Pd(Me)Cl(bis(p-Tol-imino)acenaphthene) 
• 153531-54-5 N,N'-bis(4-methoxyphenylimino)acenaphthene 
• 674322-98-6 (C₁₂H₆N₂(C₆H₄CH₃)2)Pd(C₈H₁₂OCH₃)⁽¹⁺⁾*PF₆^(1-)=(C₁₂H₆N₂(C₆H₄CH₃)2)Pd(C₈H₁₂OCH₃)PF₆ 
• 266340-73-2 chlorotricarbonyl bis(4-methylphenylimino)acenaphthene rhenium(I) 
• 1235614-37-5 [platinum(II)(phenyl)(carbonyl)(bis(4-CH₃C₆H₄-imino)acenaphthene)]tetrafluoroborate 
• 1235614-02-4 [platinum(II)(phenyl)(acetonitrile)(bis(4-MeC₆H₄-imino)acenaphthene)]tetrafluoroborate 

Relevant articles and documents

Solvatochromism, DNA binding, antitumor activity and molecular modeling study of mixed-ligand copper(II) complexes containing the bulky ligand: Bis[N-(p-tolyl)imino]acenaphthene

Four mixed-ligand copper(II) complexes of the nitrogen ligand bis[N-(p-tolyl)imino]acenaphthene 1 (p-Tol-BIAN). These complexes, namely [Cu(p-Tol-BIAN)2](ClO4)2 2, [Cu(p-Tol-BIAN)(acac)](ClO4) 3, [Cu(p-Tol-BIAN)

Unexpected coordination behavior of ruthenium to a polymeric α-diimine containing the poly[bis(arylimino)acenaphthene] fragment

Use of homogeneous catalysts poses the problem of their recovery at the end of the reaction. A possible strategy to circumvent this problem is to make the ligand part of a polymer with limited solubility. In this work, we investigated the immobilization o

Vanadyl cationic complexes as catalysts in olefin oxidation

Three new mononuclear oxovanadium(iv) complexes [VO(acac)(R-BIAN)]Cl (BIAN = 1,2-bis{(R-phenyl)imino}acenaphthene, R = H, 1; CH3, 2; Cl, 3) were prepared and characterized. They promoted the catalytic oxidation of olefins such as cyclohexene, cis-cyclooctene, and styrene with both tbhp (tert-butylhydroperoxide) and H2O2, and of enantiopure olefins (S(-)- and R(+)-pinene, and S(-)- and R(+)-limonene) selectively to their epoxides, with tbhp as the oxidant. The TOFs for styrene epoxidation promoted by complex 3 with H2O2 (290 mol mol-1V h-1) and for cis-cyclooctene epoxidation by 2 with tbhp (248 mol mol-1V h-1) are particularly good. Conversions reached 90% for several systems with tbhp, and were lower with H2O2. A preference for the internal CC bond, rather than the terminal one, was found for limonene. Kinetic data indicate an associative process as the first step of the reaction and complex [VO(acac)(H-BIAN)]+ (1+) was isolated in an FTICR cell after adding tbhp to 1. EPR studies provide evidence for the presence of a V(iv) species in solution, until at least 48 hours after the addition of tbhp and cis-cyclooctene, and cyclic voltammetry studies revealed an oxidation potential above 1 V for complex 1. DFT calculations suggest that a [VO(H-BIAN)(MeOO)]+ complex is the likely active V(iv) species in the catalytic cycle from which two competitive mechanisms for the reaction proceed, an outer sphere path with an external attack of the olefin at the coordinated peroxide, and an inner sphere mechanism starting with a complex with the olefin coordinated to vanadium. This journal is