15450-73-4Relevant articles and documents
HALF-WAVE POTENTIALS OF 1-AZA- AND 1,8-DIAZAANTHRAQUINONES
Diaz-Guerra, Luis M.,Ocana, Blanca,Perez, Jose Maria,Avendano, Carmen,Espada, Modesta,et al.
, p. 683 - 690 (2007/10/03)
The redox properties of a series of 1-azaanthracene-9,10-diones, 1,8-diazaanthracene-9,10-diones, 1,8-diazaanthracene-(1H)2,9,10-triones and 1,8-diazaanthracene-(1H,8H)2,7,9,10-tetraones have been studied.The results obtained show that the 2-pyridone moiety ia a stronger electron acceptor than the pyridine ring, in agreement with reactivity data. 1-Hydroxy-1-azaanthracene-2,9,10-triones, synthesized from 1-azaanthracene-9,10-dione-N-oxides, show redox properties close to 1,8-diazaanthracene-2,7,9,10-tetraones, and therefore the cyclic hydroxamic acid unit behaves also as an strong electron acceptor.Voltammetric half-wave first potentials correlate with the energies of the LUMO in model compounds.