154911-48-5

Basic information

• Product Name: 2-Allyl-2-methylthiocyclohexanone
• CAS NO: 154911-48-5
• Molecular Weight: 184.302
• Mol File: 154911-48-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Allyl-2-methylthiocyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Allyl-2-methylthiocyclohexanone(154911-48-5)
• EPA Substance Registry System: 2-Allyl-2-methylthiocyclohexanone(154911-48-5)

Safety Data

• Hazardous Substances Data: 154911-48-5(Hazardous Substances Data)

Upstream product

• 52190-35-9 2-(methylthio)cyclohexanone 
• 106-95-6 allyl bromide 
• 108-94-1 cyclohexanone 

Downstream Products

• 139166-40-8 2-(Prop-2-enylidene)cyclohexanone 
• 38019-50-0 2-allyl-cyclohex-2-enone 

Relevant articles and documents

SYNTHESES DE CYCLOHEXENONES α-SUBSTITUEES VIA LA THERMOLYSE DE CETOSULFOXYDES TERTIAIRES

The sulfenylation-dehydrosulfenylation method, combined with carbon-carbon bond forming reactions, has been applied to the synthesis of some α-functionalized cyclohexenones 3.Hence, the sodium anion of the 2-methylthiocyclohexanone in THF reacts with primary, allyl and benzyl halides as well as with Michael acceptors to lead to the tertiary ketosulfides 1a-j.Further oxidation by NaIO4 and thermolysis in boiling toluene of the resulting sulfoxides 2 have been performed.The scope and limitations of this strategy are also discussed. Key Words: α-functionalized cyclohexenones; tertiary ketosulfides and ketosulfoxides; sulfenylation and deshydrosulfenylation; thermolysis.