155687-70-0Relevant articles and documents
Palladium-tetraphosphine catalysed allylic substitution in water
Feuerstein, Marie,Laurenti, Dorothée,Doucet, Henri,Santelli, Maurice
, p. 2313 - 2315 (2001)
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl (C3H5)]2 system catalyses allylic amination in water with very high substrate/catalyst ratio in good yields. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
Isothiourea-catalysed chemo- and enantioselective [2,3]-sigmatropic rearrangements of N,N-diallyl allylic ammonium ylides
West, Thomas H.,Spoehrle, Stéphanie S.M.,Smith, Andrew D.
, p. 4138 - 4149 (2017/06/29)
The isothiourea-catalysed chemo- and enantioselective [2,3]-sigmatropic rearrangement of N,N-diallyl allylic ammonium ylides is explored as a key part of a route to free functionalised α-amino esters and piperidines. The [2,3]-sigmatropic rearrangement pr
Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system
Feuerstein,Laurenti,Doucet,Santelli
, p. 43 - 44 (2007/10/03)
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane/ [PdCl(C3H5)]2 system catalyses allylic amination in good yields with a very high substrate/catalyst ratio; a turnover number of 680 000 and a turnover frequency of 8125 h-1 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
