155816-67-4

Basic information

• Product Name: 2-Nonanone, 4-phenyl-
• CAS NO: 155816-67-4
• Molecular Formula: C15H22O
• Molecular Weight: 218.339
• Mol File: 155816-67-4.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: 2-Nonanone, 4-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Nonanone, 4-phenyl-(155816-67-4)
• EPA Substance Registry System: 2-Nonanone, 4-phenyl-(155816-67-4)

Safety Data

• Hazardous Substances Data: 155816-67-4(Hazardous Substances Data)

Upstream product

• 18402-83-0 (E)-non-3-en-2-one 
• 143-66-8 sodium tetraphenyl borate 
• 98-13-5 Phenyltrichlorosilane 
• 3262-89-3 triphenylboroxine 
• 4406-77-3 2-Phenyl-1,3,2-dioxaborinane 
• 14309-57-0 Non-3-en-2-on 
• 100-58-3 phenylmagnesium bromide 
• 98-80-6 phenylboronic acid 
• 1078-58-6 diphenylzinc 
• 596-38-3 9-phenyl-9H-xanthen-9-ol 
• 36519-50-3 C₆H₄C(OH)(C₆H₅)N(CH₂C₆H₅)C₆H₄ 
• 2996-92-1 phenyl trimethylsiloxane 
• 934-56-5 trimethyl(phenyl)stannane 
• 603-36-1 triphenylantimony 

Downstream Products

• 1370330-67-8 C₁₆H₂₆O 
• 1370330-68-9 C₁₆H₂₆O 

Relevant articles and documents

Silicone as an organosilicon reagent 2. Rhodium-catalyzed conjugate addition of the silicone reagent to α,β-unsaturated carbonyl compounds

The reaction of poly(phenylmethylsiloxane) with α,β-unsaturated carbonyl compounds in the presence of aqueous K2CO3 and 3 mol% of [Rh(OH)(cod)]2 gives 1,4-conjugate addition product in good yields. Arylchlorosilanes also u

Heterogeneous Gold Catalyst: Synthesis, Characterization, and Application in 1,4-Addition of Boronic Acids to Enones

The new 1 wt % Au/TiO2-UVM-7 catalyst was prepared and fully characterized. This heterogeneous catalyst proved to be active, selective and recyclable for the unprecedented gold-catalyzed 1,4-addition of various functionalized arylboronic acids to 2-cyclohexen-1-one and other selected enones using toluene as a solvent. The gold-based catalyst was recycled two times and played an active role in this reaction, and the nature of the solvent determined a remarkable change in the products' selectivities.

Efficient 1,4-addition of enones and boronic acids catalyzed by a Ni-Zn hydroxyl double salt-intercalated anionic rhodium(III) complex

Intercalation of an in situ prepared [Rh(OH)6]3- complex into an anion exchangeable Ni-Zn layered hydroxy double salt (Rh/NiZn) was demonstrated. The resulting Rh/NiZn effectively catalyzed the 1,4-addition of diverse enones and phenylboronic acids to their corresponding β-substituted carbonyl compounds. In the case of 2-cyclohexen-1-one and phenylboronic acid, a turnover frequency (TOF) of 920 h-1 based on Rh was achieved. The [Rh(OH)6]3- complex maintained its original monomeric trivalent state within the NiZn interlayer following catalysis, attributable to a strong electrostatic interaction between the NiZn host and anionic Rh(III) complex.