156093-93-5

Basic information

• Product Name: 2-Butanone, 3-[bis(phenylmethyl)amino]-1-chloro-, (3S)-
• CAS NO: 156093-93-5
• Molecular Formula: C18H20ClNO
• Molecular Weight: 301.816
• Mol File: 156093-93-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3-[bis(phenylmethyl)amino]-1-chloro-, (3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3-[bis(phenylmethyl)amino]-1-chloro-, (3S)-(156093-93-5)
• EPA Substance Registry System: 2-Butanone, 3-[bis(phenylmethyl)amino]-1-chloro-, (3S)-(156093-93-5)

Safety Data

• Hazardous Substances Data: 156093-93-5(Hazardous Substances Data)

Upstream product

• 593-71-5 Chloroiodomethane 
• 171815-89-7 (S)-ethyl 2-(dibenzylamino)propanoate 
• 100-39-0 benzyl bromide 
• 111060-49-2 N,N-dibenzyl-L-alanine benzyl ester 

Downstream Products

• 156093-94-6 (2R,3S)-3-(Dibenzylamino)-1-chlorobutan-2-ol 
• 1383617-96-6 (2S,3R,5S)-2-(dibenzylamino)-3-hydroxydodecan-5-yl octanoate 
• 1383617-87-5 (2S,3S,5R)-2-(dibenzylamino)-3-hydroxydodecan-5-yl octanoate 
• 1383618-11-8 (2S,3R,5S)-2-(dibenzylamino)-3-hydroxyoctadecan-5-yl tetradecanoate 
• 1383618-10-7 (2S,3S,5R)-2-(dibenzylamino)-3-hydroxyoctadecan-5-yl tetradecanoate 
• 1383617-97-7 (4S,6R,7S)-7-(dibenzylamino)-6-hydroxy-2-methyloctan-4-yl 3-methylbutanoate 
• 1383617-88-6 (4R,6S,7S)-7-(dibenzylamino)-6-hydroxy-2-methyloctan-4-yl 3-methylbutanoate 
• 1383617-89-7 (1S,3S,4S)-1-cyclohexyl-4-(dibenzylamino)-3-hydroxypentyl cyclohexanecarboxylate 
• 127927-42-8 (2R)-[(1S)-1-(dibenzylamino)ethyl]oxirane 
• 341524-32-1 (-)-(2S,1'S)-1-benzyl-2-[1'-(dibenzylamino)ethyl]aziridine 

Relevant articles and documents

Highly Diastereoselective Synthesis of Threo or Erythro Aminoalkyl Epoxides from α-Amino Acids

α-Chloro-α'-(dibenzylamino)methylketones 3 are synthesized in enantiomerically pure form starting from α-amino acids.Reduction of amino ketones 3 and further epoxidation affords threo aminoalkyl epoxides 6 with diastereoisomeric excess ranging between 94percent and 98percent.The synthesis of erythro amino epoxides 9 is also described by reaction of α-amino aldehydes 7 with in situ generated (halomethyl)lithium.Amino epoxides 9 were obtained with a diastereoisomeric excess ranging between 91percent and 98percent.