156387-05-2

Basic information

• Product Name: Dichloro-(4-methoxy-benzyl)-vinyl-silane
• CAS NO: 156387-05-2
• Molecular Weight: 247.196
• Mol File: 156387-05-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dichloro-(4-methoxy-benzyl)-vinyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Dichloro-(4-methoxy-benzyl)-vinyl-silane(156387-05-2)
• EPA Substance Registry System: Dichloro-(4-methoxy-benzyl)-vinyl-silane(156387-05-2)

Safety Data

• Hazardous Substances Data: 156387-05-2(Hazardous Substances Data)

Upstream product

• 61632-79-9 trichlorovinylsilane 
• 824-94-2 p-methoxybenzyl chloride 

Relevant articles and documents

SYNTHESIS OF 2-SILATETRALIN DERIVATIVES BEARING OXYGEN FUNCTIONAL GROUPS

The Grignard reagents of methoxy- or methylenedioxyphenylmethyl chlorides (12a-e) were treated with trichlorovinylsilane in THF or ether to give methoxy- or methylenedioxybenzyldichlorovinylsilanes (13a-e).The reaction of 13a-d in the presence of AlCl3 in CS2 or CH2Cl2 followed by treatment with MeOH and cyclohexylamine or Et3N afforded methoxy-2-silatetralins (16a-d).Treatment of 16a-d with MeMgI or EtMgBr in ether gave the corresponding 2,2-dimethyl- or 2,2-diethyl-2-silatetralins (17a-d or 18).Demethylation of 17a, 17b or 18 with BBr3 in CH2Cl2 furnished hydroxy-2-silatetralins (19a, 19b or 20).