156466-92-1

Basic information

• Product Name: (C₅H₅)Ru[P(C₆H₅)3]2[Si(CH₃)2C₆H₄CH₃]
• CAS NO: 156466-92-1
• Molecular Weight: 840.034
• Mol File: 156466-92-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Ru[P(C₆H₅)3]2[Si(CH₃)2C₆H₄CH₃](CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Ru[P(C₆H₅)3]2[Si(CH₃)2C₆H₄CH₃](156466-92-1)
• EPA Substance Registry System: (C₅H₅)Ru[P(C₆H₅)3]2[Si(CH₃)2C₆H₄CH₃](156466-92-1)

Safety Data

• Hazardous Substances Data: 156466-92-1(Hazardous Substances Data)

Upstream product

• 34692-09-6 (η5-cyclopentadienyl)methylbis(triphenylphosphine)ruthenium 
• 1432-39-9 dimethyl-p-tolylsilane 

Relevant articles and documents

Nonphotochemical synthesis and structure of the first donor-stabilized [bis(silylene)]ruthenium complex

The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph3P)Ru(SiMe2 - O(Me) - SiMe2), has been synthesized by the thermal reaction of CpRu(PPh3)2Me with HMe2SiSiMe2OMe. The X-ray crystal structure analysis of this complex revealed its distorted-piano-stool structure, containing a RuSi2O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.