15724-86-4

Basic information

• Product Name: (E)-β-Chloroacrylophenone
• Synonyms: (E)-β-Chloroacrylophenone;(E)-3-chloro-1-phenylprop-2-en-1-one
• CAS NO: 15724-86-4
• Molecular Formula: C₉H₇ClO
• Molecular Weight: 166.60428
• Mol File: 15724-86-4.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 232.5°C at 760 mmHg
• Flash Point: 111.7°C
• Appearance: /
• Density: 1.169g/cm³
• Vapor Pressure: 0.0589mmHg at 25°C
• Refractive Index: 1.556
• CAS DataBase Reference: (E)-β-Chloroacrylophenone(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-β-Chloroacrylophenone(15724-86-4)
• EPA Substance Registry System: (E)-β-Chloroacrylophenone(15724-86-4)

Safety Data

• Hazardous Substances Data: 15724-86-4(Hazardous Substances Data)

Usage

General Description

(E)-β-Chloroacrylophenone is a chemical compound with the molecular formula C9H7ClO. It is a beta-chloro ketone that is commonly used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. (E)-β-Chloroacrylophenone is also known for its use in organic synthesis and as a building block for various chemical reactions. It is a pale yellow to brown liquid that is typically stored in a cool, dry place away from direct sunlight and sources of ignition. (E)-β-Chloroacrylophenone is considered to have moderate acute toxicity and should be handled with care in a well-ventilated area or with the use of appropriate personal protective equipment.

InChI:InChI=1/C9H7ClO/c10-7-6-9(11)8-4-2-1-3-5-8/h1-7H/b7-6+

Upstream product

• 41125-10-4 benzoylacetaldehyde sodium salt 
• 98-88-4 benzoyl chloride 
• 74-86-2 acetylene 
• 18609-60-4 (Z)-3-hydroxy-1-phenylprop-2-en-1-one 
• 75-01-4 chloroethylene 
• 15397-33-8 3-Oxo-3-phenylpropanal 
• 3306-07-8 1-benzoyl-2-chloroethene 
• 93-55-0 1-phenyl-propan-1-one 
• 104755-22-8 C₁₅H₁₄Cl₂OSe 
• 98-86-2 acetophenone 
• 70-11-1 α-bromoacetophenone 
• 71-43-2 benzene 
• 768-03-6 Phenyl vinyl ketone 
• 3623-15-2 phenyl propargyl ketone 

Downstream Products

• 40685-20-9 (E)-3-methoxy-1-phenylprop-2-en-1-one 
• 4492-01-7 1,3-diphenyl-1H-pyrazole 
• 2458-26-6 3-phenylpyrazole 
• 1702-14-3 ethyl 2-methyl-6-phenylnicotinate 
• 83241-28-5 1,1-Dimethyl-2-((Z)-3-oxo-3-phenyl-propenyl)-isothiourea; compound with perchloric acid 
• 107113-30-4 (E)-3-(3-Methyl-pyrazol-1-yl)-1-phenyl-propenone 
• 107113-37-1 (E)-3-Benzotriazol-2-yl-1-phenyl-propenone 
• 87172-18-7 (E)-1-phenyl-3-[(2,4,6-trimethylphenyl)]prop-2-en-1-one 
• 106576-42-5 1-phenyl-3-p-tolylsulfanyl propenone 
• 49660-41-5 triethyl-(3-oxo-3-phenyl-propenyl)-ammonium; chloride 
• 1131-80-2 (E)-3-(N,N-dimethylamino)-1-phenyl-2-propen-1-one 
• 872789-09-8 (12-chloro-9,10-dihydro-9,10-ethano-anthracen-11-yl)-phenyl ketone 
• 4173-44-8 (E,E)-6-phenyl-3,5-hexadien-2-one 
• 2161305-12-8 (Z)-3-((3-nitrophenyl)amino)-1-phenylprop-2-en-1-one 

Relevant articles and documents

Process for the preparation of beta-chlorovinyl ketones

β-Chlorovinyl ketones are prepared by reacting acyl chlorides with acetylene in chloroaluminate-containing ionic liquids. The process gives high yields without formation of tarry byproducts.

A novel and simple route for the synthesis of 3,4-disubstituted pyrroles

A new class of 3,4-disubstituted pyrroles has been prepared by the reaction of 1-aroyl-2-arylsulfonylethenes and 1,2-diarylsulfonylethenes with tosyl methyl isocyanide.

A novel route for the synthesis of unsaturated oxo sulfones and bissulfones

The reaction between vinyl chloride and aroyl/arylsulfonyl chloride under Friedel-Craft's reaction conditions was the basis for the synthesis of unsaturated oxo sulfones and bissulfones.