157609-76-2Relevant articles and documents
(N-Methylphenylsulfoximidoyl)methyllithium: A versatile reagent for the determination of absolute configuration of six-membered ring ketones
Preite,Gonzalez-Sierra,Zinczuk,Ruveda
, p. 503 - 506 (2007/10/02)
The diastereotopic chemical shift differences of the 1H and 13C NMR signals of the adducts formed by addition of (N-methylphenylsulfoximidoyl)methyllithium (2) to cyclic ketones has been studied. The stereodifferentiation of the proton and carbon atoms follow a very regular pattern annd the rule that can be drawn provides an alternative and complementary method to earlier procedures for the determinations of absolute configuration of six-membered ring ketones.