157959-02-9

Basic information

• Product Name: (bromo)(carbonyl)4(PPh₂C₂H₄PPh₂)vanadium(I)
• CAS NO: 157959-02-9
• Molecular Weight: 641.311
• Mol File: 157959-02-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (bromo)(carbonyl)4(PPh₂C₂H₄PPh₂)vanadium(I)(CAS DataBase Reference)
• NIST Chemistry Reference: (bromo)(carbonyl)4(PPh₂C₂H₄PPh₂)vanadium(I)(157959-02-9)
• EPA Substance Registry System: (bromo)(carbonyl)4(PPh₂C₂H₄PPh₂)vanadium(I)(157959-02-9)

Safety Data

• Hazardous Substances Data: 157959-02-9(Hazardous Substances Data)

Upstream product

• 13985-78-9 tetraethylammonium hexacarbonylvanadium(-1) 
• 18820-82-1 Pyridine hydrobromide 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Relevant articles and documents

Zur Reaktivitaet von Hydridocarbonylvanadium-Komplexen: Darstellung und Charakterisierung von Alkylvanadium-Komplexen, und die Molekuelstruktur von trans-

Various ?-alkylvanadium complexes of the general formula RV(CO)npm (n = 4, 3; pm is an m-dentate phosphine coordinating through (6 - n) P-functions) have been prepared by photo-reaction between the hydrido precursors HV(CO)npm and alkenes, and characterized by IR- and 51V NMR spectroscopy.The preparation of the new phosphines Me2P(CH2)3P(iPr)2 and iPrP(CH2CH2CH2PMe2)2 is described. trans- crystallizes in the space group P1 with the following cell parameters: a = 1012.1(9), b = 1012.9(6), c = 1224.7(9) pm, a = 105.780(6), β = 102.601(7)deg.